Trans Tianjin Univ论文导读 | 2020年第4期
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Trans Tianjin Univ
2020年第4期
COVER STORY
Magnesium-ion batteries (MIBs) have attracted increasing attention because of their low cost, safety, and natural abundance.
However, the cycling performance of MIBs remains poor because of the anode side of Mg metal, such as the large volume change during the discharge/charge process and sluggish Mg ion diffusion in a dense SEI layer.
Therefore, Profs. Sun and Yang et al. investigated FePS3, a classical 2D layered material with transition metal phosphorous trichalcogenides, as an anodematerial for Mg ion batteries with density functional theory (DFT).
The results show that the theoretical specific capacity of the FePS3 monolayeris 585.6 mA h/g with a relatively low average voltage of 0.483 V (vs.Mg/Mg2+), which is favorable to a high energy density.
The slight change in volume and good electronic conductivity of bulk FePS3 are beneficial to electrode stability during cycling (see the article on pages 248-255).
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Transactions of Tianjin University
天津大学学报（英文版)
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