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Sci. China Chem. 2019年第4期目录

SCIENCE CHINA Chemistry

2019, Issue 4

Cover Story

Halogen effects have been observed on phenylethynyl palladium(II) complexes for living polymerization of isocyanides. The coordinated halogen anions can significantly influence the kinetics of polymerization, with the observed order of reaction rates being I > Br > Cl. DFT calculations were then employed to understand the detailed mechanism and the halogen effects in this insertion polymerization process (see the article by Yaqi Wang, Yu Chen, Zhiqiang Jiang, Fang Liu, Fang Liu, Yuanyuan Zhu,Yong Liang & Zongquan Wu on pages 491–499).


01Highlight

Electron-deficient core fused-ring based non-fullerene acceptor enables over 15% efficiency in single junction organic solar cells

Hongzheng Chen 

Sci China Chem2019, 62(4): 403–404


02Highlight

Achieving high efficiency and low voltage loss simultaneously for non-fullerene organic solar cells

Liwei Yang, Yanyan Jia,  He Yan 

Sci China Chem2019, 62(4): 405–406


03Highlight

Single-molecule DNA logic nanomachines based on origami

Yunyi Liu, Xiaoxiao Hu, Ting Fu, Ruowen Wang, Weihong Tan

Sci China Chem2019, 62(4): 407–408


04Review

Celastrol as a tool for the study of the biological events of metabolic diseases

Gongcai Lan, Jie Zhang, Wenbo Ye, Fan Yang, Ang Li, Weiwei He, Wei-Dong Zhang 

Sci China Chem2019, 62(4): 409–416


05Review

Metal-organic framework based nanomaterials for electrocatalytic oxygen redox reaction

Kexin Zhang, Wenhan Guo, Zibin Liang, Ruqiang Zou

Sci China Chem2019, 62(4): 417–429

【延伸阅读】金属有机骨架及其衍生纳米材料在电化学氧催化反应中的应用


06Communication

A novel metal-free amorphous room-temperature phosphorescent polymer without conjugation

Disen Wang, Xi Wang, Chao Xu, Xiang Ma 

Sci China Chem2019, 62(4): 430–433


07Article

Photogenerated singlet oxygen over zeolite-confined carbon dots for shape selective catalysis

Qiu-Ying Yu, Guang-Yao Zhai, Tian-Lu Cui, Hui Su, Zhong-Hua Xue, Jun-Jun Zhang, Peter J. Pauzauskie, Shin-ichi Hirano, Xin-Hao Li, Jie-Sheng Chen

Sci China Chem2019, 62(4): 434–439


08Article

Vinyl-functionalized multicolor benzothiadiazoles: design, synthesis, crystal structures and mechanically-responsive performance

Jianhua Chen, Fengying Ye, Yan Lin, Zhao Chen, Shenghua Liu, Jun Yin 

Sci China Chem2019, 62(4): 440–450


09Article

Rational design of a visible-light photochromic diarylethene: a simple strategy by extending conjugation with electron donating groups

Shanliang Tang, Fengling Song, Meiheng Lu, Keli Han, Xiaojun Peng 

Sci China Chem2019, 62(4): 451–459


10Article

Metal-free C3-alkoxycarbonylation of quinoxalin-2(1H)-ones with carbazates as ecofriendly ester sources

Long-Yong Xie, Sha Peng, Tai-Gang Fan, Yan-Fang Liu, Meng Sun, Li-Lin Jiang, Xing-Xing Wang, Zhong Cao, Wei-Min He

Sci China Chem2019, 62(4): 460–464


11Article

A ratiometric fluorescent sensor for tracking Cu(I) fluctuation in endoplasmic reticulum

Jungu Guo, Hao Yuan, Yuncong Chen, Zhongyan Chen, Menglong Zhao, Liang Zou, Yi Liu, Zhipeng Liu, Qiang Zhao, Zijian Guo, Weijiang He 

Sci China Chem2019, 62(4): 465–474


12Article

Lewis acid/base modulation in β-diiminate zinc-catalyzed switchable ring-opening polymerization of rac-lactide

Pan Zhang, Minhui Zhao, Wenmin Pang, Changle Chen 

Sci China Chem2019, 62(4): 475–478


13Article

Selectivity enhancement of quaternized poly(arylene ether ketone) membranes by ion segregation for vanadium redox flow batteries

Yu Chen, Zhongcheng Liu, Meijin Lin, Qilang Lin, Bihai Tong, Dongyang Chen

Sci China Chem2019, 62(4): 479–490


14Article

Halogen effects on phenylethynyl palladium(II) complexes for living polymerization of isocyanides: a combined experimental and computational investigation

Yaqi Wang, Yu Chen, Zhiqiang Jiang, Fang Liu, Fang Liu, Yuanyuan Zhu, Yong Liang, Zongquan Wu 

Sci China Chem2019, 62(4): 491–499

【延伸阅读】炔钯配合物引发异腈单体活性聚合的卤素效应


15Article

Flexible ITO-free organic solar cells over 10% by employing drop-coated conductive PEDOT:PSS transparent anodes

Huiqin Cui, Wei Song, Billy Fanady, Ruixiang Peng, Jianfeng Zhang, Jiaming Huang, Ziyi Ge 

Sci China Chem2019, 62(4): 500–505

【延伸阅读】滴涂法大规模制备高性能柔性无ITO有机太阳能电池


16Article

Screen efficiency comparisons of decision tree and neural network algorithms in machine learning assisted drug design

Qiumei Pu, Yinghao Li, Hong Zhang, Haodong Yao, Bo Zhang, Bingji Hou, Lin Li, Yuliang Zhao, Lina Zhao

Sci China Chem2019, 62(4): 506–514


17Article


Ion-vacancy coupled charge transfer model for ion transport in concentrated solutions

Yu Gao, Jun Huang, Yuwen Liu, Jawei Yan, Bingwei Mao, Shengli Chen

Sci China Chem2019, 62(4): 515–520


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