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《纳米研究》2020年第10期目录

编辑部 NanoResearch 2022-09-25


Review Articles


Nanomaterials for radiotherapeutics-based multimodal synergistic cancer therapy

Xi Yang1, Ling Gao1, Qing Guo2, Yongjiang Li1, Yue Ma1, Ju Yang1, Changyang Gong1,*, and Cheng Yi1,*

1 Sichuan University, China

2 Taizhou People’s Hospital, China

In this review, we discuss opportunities for a synergistic cancer therapy by combining radiotherapy based on nanomaterials designed for chemotherapy, photodynamic therapy, photothermal therapy, gas therapy, genetic therapy, and immunotherapy. 

2579–2594





Nanotechnologies for enhancing cancer immunotherapy

Jingxian Yang, Chunhui Wang, Shuo Shi*, and Chunyan Dong*

Tongji University, China

Based on the medical introduction of cancer immunotherapy and the application of nanomaterial delivery system in tumor treatments, this review summarizes the recent advances in nanoplatform-based technology combined with the hot spots in the field of immunotherapy. The aim is to develop better immunotherapy nano-tools for clinical use under the guidance of existing research results.

2595–2616





Advances of biological-camouflaged nanoparticles delivery system

Yanlin Chen and Kui Cheng*

Southern Medical University, China

Different cell membrane-coated nanoparticles are used for tumor therapy.

2617–2624



Research Articles


Gold-vapor-assisted chemical vapor deposition of aligned monolayer WSe2 with large domain size and fast growth rate

Mingrui Chen, Anyi Zhang, Yihang Liu, Dingzhou Cui, Zhen Li, Yu-Han Chung, Sai Praneetha Mutyala, Matthew Mecklenburg, Xiao Nie, Chi Xu, Fanqi Wu, Qingzhou Liu, and Chongwu Zhou*

University of Southern California, Los Angeles, USA

Gold vapor was introduced into the chemical vapor deposition (CVD) process as a catalyst to assist the growth of WSe2. Highly aligned monolayer WSe2 triangular flakes with large domain size (130 μm) and fast growth rate (4.3 μm·s−1), and continuous monolayer films with good uniformity were achieved.

2625–2631





NIR-IIb excitable bright polymer dots with deep-red emission for in vivo through-skull three-photon fluorescence bioimaging

Nuernisha Alifu1,2, Abudureheman Zebibula2, Hequn Zhang2, Huwei Ni2, Liang Zhu2, Wang Xi2,*, Yalun Wang2, Xueliang Zhang1,*, Changfeng Wu3, and Jun Qian2,*

1 Xinjiang Medical University, China

2 Zhejiang University, China

3 South University of Science and Technology, China

The near-infrared IIb (NIR-IIb) excitable deep-red emissive semiconducting polymer dots (P-dots) with bright three-photon fluorescence (3PF) under 1,550 nm fetmosecond laser excitation were prepared and functionalized. Then the P-dots were utilized for in vivo 3PF cerebral vasculature microscopic imaging of mice with and without the brain skull.

2632–2640





Unexpected Kirkendall effect in twinned icosahedral nanocrystals driven by strain gradient

Jingbo Huang1, Yucong Yan1,2, Xiao Li1, Xurong Qiao3, Xingqiao Wu1, Junjie Li1, Rong Shen1, Deren Yang1,*, and Hui Zhang1,*

1 Zhejiang University, China

2 SAIC Motor Corporation Limited, China

3 China University of Petroleum, China

Kirkendall effect unexpectedly takes place when diffusing intrinsically faster Cu atoms into Pd icosahedra. The strain gradient arising from the multiple twins of the icosahedra is the key to drive such Kirkendall effect, leading to the formation of hollow structures.

2641–2649





Unveiling nanoplates-assembled Bi2MoO6 microsphere as a novel anode material for high performance potassium-ion batteries

Junxian Hu, Yangyang Xie, Jingqiang Zheng, Yanqing Lai, and Zhian Zhang*

Central South University, China

Bi2MoOmicrosphere assembled by two-dimensional (2D) nanoplate exhibits good potassium storage performance and performs a combination mechanism of conversion reaction and alloying/dealloying reaction.

2650–2657





Tunable colors and conductivity by electroless growth of Cu/Cu2O particles on sol-gel modified cellulose

Justus Landsiedel1,*, Waleri Root1, Christian Schramm1, Alexander Menzel1, Steffen Witzleben2, Thomas Bechtold1, and Tung Pham1,*

1 University of Innsbruck, Austria

2 Bonn-Rhein-Sieg University of Applied Sciences, Germany

In situ growth and immobilization of copper nanoparticles on cellulose textiles results in tunable coloration and electrical conductivities.

2658–2664





An efficient visible-light photocatalyst for CO2 reduction fabricated by cobalt porphyrin and graphitic carbon nitride via covalent bonding

Shufang Tian, Sudi Chen, Xitong Ren, Yaoqing Hu, Haiyan Hu, and Jiajie Sun*, and Feng Bai*

Henan University, China

The functional integrated visible light photocatalyst for CO2 reduction was prepared by combining homogeneous catalyst metalloporphyrin CoTDPP with the heterogeneous photosensitizer graphitic carbon nitride via covalent bonding. The strong interaction between catalyst unit and photosensitizer unit is conductive to the separation and migration of photogenerated charge carriers and the metalloporphyrin CoTDPP not only provides single site catalytic center but also effectively broadens the visible light absorption range of the functional integrated photocatalyst. The g-CNU-CoTDPP exhibited excellent photocatalytic performance for CO2 reduction with CO as the major product at an average evolution rate of 57 μmol/(g·h) and the selectivity of 79% over competing H2 evolution.

2665–2672





Bonding VSe2 ultrafine nanocrystals on graphene toward advanced lithium-sulfur batteries

Wenzhi Tian, Baojuan Xi, Yu Gu, Qiang Fu, Zhenyu Feng, Jinkui Feng, and Shenglin Xiong*

Shandong University, China

VSe2 ultrafine nanocrystals immobilized on the nitrogen-doped graphene hybrid nanosheets (VSe2 NC@NG) as a new polysulfides barrier are synthesized via a self-template strategy, which possess more exposed sulfiphilic planes of VSe2, as well as benefit the uniform nucleation of Li2S—making this system an excellent polysulfides barrier for lithium–sulfur batteries. 

2673–2682





A photoactive process cascaded electrocatalysis for enhanced methanol oxidation over Pt-MXene-TiO2 composite

Yue Sun, Yunjie Zhou, Yan Liu, Qingyao Wu, Mengmeng Zhu, Hui Huang, Yang Liu*, Mingwang Shao*, and Zhenhui Kang*

Soochow University, China

A Pt-MXene-TiO2 composite exhibits highly efficient methanol oxidation reaction (MOR) performance with light irradiation via a photo-active cascaded electro-catalytic process.

2683–2690





Trimetallic Au@PdPb nanowires for oxygen reduction reaction

Xian Jiang1,2,3, Yuexin Xiong3, Ruopeng Zhao2, Jiancheng Zhou1,*, Jong-Min Lee2,*, and Yawen Tang3,*

1 Southeast University, China

2 Nanyang Technological University, Singapore

3 Nanjing Normal University, China

Trimetallic Au@PdPb nanowires (NWs) are synthesized by using pre-fabricated ultrathin Au nanowires as the one-dimensional template. The Au@PdPb NWs are demonstrated to be active and stable for the oxygen reduction reaction (ORR), much better than those of commercial Pd black and bimetallic Au@Pd NWs. Considering facile synthesis method and excellent ORR performance, the developed Au@PdPb NWs may have great potential in the field of fuel cells.

2691–2696





Controlling human platelet activation with calcium-binding nanoparticles

David Cabrera1, Karen Walker1, Sandhya Moise1,2, Neil D. Telling1, and Alan G. S. Harper1,*

1 Keele University, UK

2 University of Bath, UK

Calcium-binding magnetic nanoparticles are an effective anti-platelet nanomedicine. These nanoparticles function by chelating calcium in the open canalicular system (OCS; a space formed by the infolding of the platelet plasma membrane) interfering with normal Ca2+ signaling pathways that drive platelet aggregation.

2697–2705





iRGD-reinforced, photo-transformable nanoclusters toward cooperative enhancement of intratumoral penetration and antitumor efficacy

Jing Yan1, Rongying Zhu2, Fan Wu1, Ziyin Zhao1, Huan Ye1, Mengying Hou1, Yong Liu1,*, and Lichen Yin1,*

1 Soochow University, China

2 The Second Affiliated Hospital of Soochow University, China

iRGD-assisted and photo-transformable nanoclusters mediate cooperative enhancement of intratumoral penetration and programmed tumor ablation.

2706–2715





Reliable high temperature, high humidity flexible thin film encapsulation using Al2O3/MgO nanolaminates for flexible OLEDs

Ki Suk Kang1, So Yeong Jeong1, Eun Gyo Jeong2,*, and Kyung Cheol Choi1,*

1 Korea Advanced Institute of Science and Technology (KAIST), Republic of Korea

2 Chonnam National University, Republic of Korea

An Al2O3/MgO nanolaminate was fabricated and it exhibited greatly improved hydrolysis resistance in harsh environmental conditions than Al2O3. An actual encapsulated operating device was tested under bending stress and the device demonstrated excellently stable shelf-lifetime in a harsh environment.

2716–2725





Zwitterion-assisted transition metal dichalcogenide nanosheets for scalable and biocompatible inkjet printing

Hyeokjung Lee, Min Koo, Chanho Park, Madhumita Patel, Hyowon Han, Tae Hyun Park, Pawan Kumar, Won-Gun Koh, and Cheolmin Park*

Yonsei University, Republic of Korea

Various two-dimensional transition metal dichalcogenide (TMD) nanosheets, in addition to few-layered graphene, are inkjet-printed using a novel liquid-phase exfoliation process based on zwitterionic dispersants in water. Aqueous, biocompatible zwitterionic inks with TMD nanosheets are suitable for conventional office inkjet printing, giving rise to the mechanically flexible, printed arrays of two-terminal, parallel type photodetectors with pixelated TMD channels.

2726–2734





A library of carbon-supported ultrasmall bimetallic nanoparticles

Shi-Long Xu1, Shan-Cheng Shen1, Ze-Yue Wei1, Shuai Zhao1, Lu-Jie Zuo1, Ming-Xi Chen1, Lei Wang1, Yan-Wei Ding1, Ping Chen2, Sheng-Qi Chu3, Yue Lin1,*, Kun Qian1,*, and Hai-Wei Liang1,*

1 University of Science and Technology of China, China

2 Anhui University, China

3 Institute of High Energy Physics, Chinese Academy of Sciences, China

A library of ultrasmall bimetallic nanoparticles with average particle sizes ranging from 0.7 to 1.4 nm are prepared on mesoporous sulfur-doped carbon supports. The synthetic approach is based on the strong chemical interaction between the doped sulfur atoms on carbons and metals, which suppresses the metal aggregation during H2-reduction and ensures the formation of small-sized and alloyed bimetallic nanoparticles.

2735–2740





Enhancing through-plane thermal conductivity of fluoropolymer composite by developing in situ nano-urethane linkage at graphene–graphene interface

Muhammad Maqbool1, Haichang Guo1, Akbar Bashir1, Ali Usman1, Adeel Y. Abid1, Guansong He2, Yanjuan Ren1, Zeeshan Ali1,3, and Shulin Bai1,*

1 Peking University, China

2 Institute of Chemical Materials, Chinese Academy of Engineering Physics (CAEP), China

3 National University of Sciences and Technology (NUST),  Parkistan

The nanourethane linkage (NUL) based graphene (Gr) and carbon fibers (CFs) 3D architecture (NUL-Gr/CFs) is fabricated, which is further employed in making composite of polyvinylidene fluoride (PVDF). Herein, toluene diisocyanate (TDI) is utilized to develop NUL.

2741–2748





A non-nucleophilic gel polymer magnesium electrolyte compatible with sulfur cathode

Haiyan Fan1,2, Yuxing Zhao3, Jianhua Xiao3, Jifang Zhang3, Min Wang1,2, and Yuegang Zhang2,3,*

1 University of Science and Technology of China, China

2 Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, China

3 Tsinghua University, China

Gel-type electrolytes are advantageous in terms of safety and flexibility compared with liquid electrolytes. Here, a non-nucleophilic gel-type magnesium chloride-(fluorinated tetraethylene glycolic)borate (MgCl-FTGB) electrolyte is synthesized. Mg deposition and stripping can be conducted with high rate and low overpotential in this electrolyte. It is also compatible with S cathode and enables stable cycling of Mg/S batteries.

2749–2754





Hybrids of gold nanoparticles and oligo(p-phenyleneethynylene)s end-functionalized with alkynylruthenium groups: Outstanding two-photon absorption in the second biological window

Cristóbal Quintana1, Mahbod Morshedi1, Jun Du1, Joseph P. L. Morrall1, Jan K. Zarba2, Marek Samoc2, Marie P. Cifuentes1, and Mark G. Humphrey1,*

1 Australian National University, Australia

2 Wroclaw University of Science and Technology, Poland

Oligo(p-phenyleneethynylene)s (OPEs) end-capped with (alkynyl)bis(diphosphine)ruthenium and thiol/thiolate groups stabilize ca. 2 nm diameter gold nanoparticles (AuNPs) affording OPE/AuNP hybrids that display long-term stability in solution (more than a month), good solubility in organic solvents, reversible ruthenium-centered oxidation, and transparency beyond 800 nm, and possess very strong nonlinear absorption activity at the first biological window, and unprecedented two-photon absorption activity in the second biological window (σ2 up to 38,000 GM at 1,050 nm).

2755–2762





Edge-enriched MoS2 for kinetics-enhanced potassium storage

Guangshen Jiang1, Xiaosa Xu1, Haojie Han1, Changzhen Qu1, Hlib Repich1, Fei Xu1,2,*, and Hongqiang Wang1,*

1 Northwestern Polytechnical University, China

2 Technische Universität Dresden, Germany

Edge-enriched MoS2 (EE-MoS2) was designed with bicontinuous mesoscale skeletons and mesopores, rendering its intrinsic layer spacing more accessible for K+ and accelerating conversion kinetics, thus realizing enhanced capacity and high rate capability.

2763–2769





Amplified fluorescence of Mg2+ selective red-light emitting carbon dot in water and direct evaluation of creatine kinase activity

Saptarshi Mandal, Jagannath Pal, Ranga Subramanian, and Prolay Das*

Indian Institute of Technology Patna, India

Magnesium(II) selective fluorescence enhancement of carbon dot was applied to the direct detection of creatine kinase.

2770–2776





Advanced Ni-Nx-C single-site catalysts for CO2 electroreduction to CO based on hierarchical carbon nanocages and S-doping

Yiqun Chen1, Yuejian Yao1, Yujian Xia2, Kun Mao1, Gongao Tang1, Qiang Wu1,*, Lijun Yang1,*, Xizhang Wang1, Xuhui Sun2, and Zheng Hu1,*

1 Nanjing University, China

2 Soochow University, China

Ni-Nx-C single-site catalyst based on the unique hierarchical carbon nanocages exhibits a high plateau of Faradaic efficiency for CO2 electroreduction to CO in a wide range of −0.6 to −1.0 V. S-doping further enhances the CO partial current by 68% and the Faradaic efficiency to 95% at −0.8 V.

2777–2783





Regulating surface state of WO3 nanosheets by gamma irradiation for suppressing hydrogen evolution reaction in electrochemical N2 fixation

Yanqiu Du, Cheng Jiang, Li Song, Bin Gao, Hao Gong, Wei Xia, Lei Sheng, Tao Wang*, and Jianping He*

Nanjing University of Aeronautics and Astronautics, China

The WO3 nanosheets with oxygen vacancy were designed for nitrogen reduction reaction (NRR) and tuned electroinc state to suppress hydrogen evolution reaction (HER).

2784–2790





The enhanced protective effects of salvianic acid A: A functionalized nanoparticles against ischemic stroke through increasing the permeability of the blood-brain barrier

Yaru Li1,2, Xiaojie Zhang1, Zhifeng Qi3,*, Xueling Guo1,2, Xiaopeng Liu4, Wenjuan Shi3, Yang Liu1,2,*, and Libo Du1,2,*

1 Institute of Chemistry, Chinese Academy of Sciences, China

2 Graduate School, University of Chinese Academy of Sciences, China

3 Xuanwu Hospital of Captital Medical University, China

4 The Second Hospital of Hebei Medical University, China

A new type of nanoparticle linked with salvianic acid A (SA) and modified with a targeting peptide, COG1410, that targets the lipoprotein receptors (LPR) on the surface of vascular endothelial cells is fabricated. The potential mechanism of action of the T-SA-NPs in damaged neurons as a result of ischemic stroke is proposed. The internalization of the T-SA-NPs allows the released SA to protect the cells from oxidative stress damage that is induced by ischemic stroke.

2791–2802





Construction of self-sensitized LiErF4:0.5% Tm3+@LiYF4 upconversion nanoprobe for trace water sensing

Ling Zhang1, Xiaodan Li1, Wang Wang2, Xu Zhao1, Xu Yan1, Chenguang Wang1, Haoqiang Bao1, Yang Lu1, Xianggui Kong2, Fengmin Liu1, Xiaomin Liu1,*, and Geyu Lu1,*

1 Jilin University, China

2 Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Science, China

We have achieved the strong red upconversion emission based on LiErF4 system, i.e., LiErF4@LiYF4 and its relevant derivative LiErF4: 0.5% Tm3+@LiYF4, which exhibit strong monochromic red emission under multiband near-infrared (NIR) excitation (e.g., ~ 808, ~ 980 and ~ 1,530 nm). The Er3+ ions enriched nature makes LiErF4: 0.5% Tm3+@LiYF4 nanoparticles very sensitive for trace water sensing with detection limit of 30 ppm in acetonitrile, 50 ppm in dimethyl sulfoxide (DMSO), and 58 ppm in N,N-dimethyl-formamide (DMF) under safe excitation of 808 nm.

2803–2811





Plasmonic coupling-enhanced in situ photothermal nanoreactor with shape selective catalysis for C–C coupling reaction

Zhenxing Li1,*, Yixuan Gong1, Xin Zhang1, Yangyang Wen1, Jiasai Yao1, Mingliang Hu1, Miao He1, Jiahao Liu1, Rui Li1, Fuqiang Wang2, and Chuanxin Zhang2,*

1 China University of Petroleum (Beijing), China

2 Harbin Institute of Technology at Weihai, China

A multifunctional nanoreactor for C–C coupling reaction was successfully designed via encapsulating the core-shell Cu@Ni nanocubes into ZIF-8 (Cu@Ni@ZIF-8).

2812–2818





A general bottom-up synthesis of CuO-based trimetallic oxide mesocrystal superstructures for efficient catalytic production of trichlorosilane

Hezhi Liu1,3, Yongjun Ji2,1,*, Jing Li1, Yu Zhang1, Xueguang Wang3, Haijun Yu4, Dingsheng Wang5, Ziyi Zhong6,7, Lin Gu8, Guangwen Xu9, Yadong Li5, and Fabing Su1,9,10,*

1 Institute of Process Engineering, Chinese Academy of Sciences, China

2 Beijing Technology and Business University, China

3 Shanghai University, China

4 Beijing University of Technology, China

5 Tsinghua University, China

6 Guangdong Technion–Israel Institute of Technology (GTIIT), China

7 Technion–Israel Institute of Technology (IIT), Israel

8 Institute of Physics, Chinese Academy of Sciences, China

9 Shenyang University of Chemical Technology, China

10 Zhongke Langfang Institute of Process Engineering, China

A general bottom-up synthesis of CuO-based trimetallic oxide mesocrystals (denoted as CuO-M1Ox-M2Oy, where M1 and M2 = Zn, In, Fe, Ni, Mn, and Co) is reported using a simple precipitation method followed by a hydrothermal treatment and a topotactic transformation via calcination.

2819–2827





Atomically precise metal-chalcogenide semiconductor molecular nanoclusters with high dispersibility: Designed synthesis and intracluster photocarrier dynamics

Jiaxu Zhang1, Chaochao Qin2, Yeshuang Zhong3, Xiang Wang1, Wei Wang1,3, Dandan Hu1, Xiaoshuang Liu1, Chaozhuang Xue1, Rui Zhou1, Lei Shen4, Yinglin Song1, Dingguo Xu3, Zhien Lin3, Jun Guo1, Haifeng Su4, Dong-Sheng Li5, and Tao Wu1,*

1 Soochow University, China

2 Henan Normal University, China

3 Sichuan University, China

4 Xiamen University, China

5 China Three Gorges University, China

A unique “core–shell” charge transfer relaxation dynamics directed by composition variation was observed in a group of atomically precise semiconductor nanoclusters with targeted high dispersibility in solution.

2828–2836





Efficient synthesis of lithium rare-earth tetrafluoride nanocrystals via a continuous flow method

Jinsong Sui, Junyu Yan, Kai Wang*, and Guangsheng Luo

Tsinghua University, China

A continuous method for synthesizing LiREF4 nanocrystals was developed with the assistant of a new precursor solution and a silicon carbide (SiC) reactor. The new precursor solution employed trioctylamine (TOA) as the solvent, which prevented the generation of unnecessary solid components, and the space-time yield of the continuous method is about 15 times of that traditional batch reactions.

2837–2846





New approach for time-resolved and dynamic investigations on nanoparticles agglomeration

Neda Iranpour Anaraki1,2, Amin Sadeghpour1, Kamran Iranshahi1,3, Claudio Toncelli1, Urszula Cendrowska4, Francesco Stellacci4, Alex Dommann1,5, Peter Wick2, and Antonia Neels1,2,*

1 Swiss Federal Laboratories for Materials Science and Technology, Switzerland

2 University of Fribourg, Switzerland

3 Swiss Federal Institute of Technology, Switzerland

4 EPFL, Switzerland,

5 University of Bern, Switzerland 

An advanced label-free method based on small-angle X-ray scattering (SAXS) and microfluidic for in situ measurements of dynamic processes, namely nanoparticles agglomeration in biological media is reported.

2847–2856





Broadband electroluminescence from reverse breakdown in individual suspended carbon nanotube pn-junctions

Bo Wang1, Sisi Yang1, Yu Wang1, Younghee Kim2, Ragib Ahsan1, Rehan Kapadia1, Stephen K. Doorn2, Han Htoon2, and Stephen B. Cronin1,*

1 University of Southern California, Los Angeles, USA

2 Los Alamos National Laboratory, USA

We report broadband electroluminescence via highly efficient light emission through an avalanche breakdown process from individual suspended carbon nanotube (CNT) dual-gate field effect transistor (FET) devices. The corresponding spectra obtained via thermal emission are considerably narrower than those obtained under reverse breakdown.

2857–2861





High N-doped hierarchical porous carbon networks with expanded interlayers for efficient sodium storage

Dongqin Su1, Man Huang1, Junhao Zhang1,*, Xingmei Guo1, Jiale Chen1, Yanchun Xue1, Aihua Yuan1,*, and Qinghong Kong2

1 Jiangsu University of Science and Technology, China

2 Jiangsu University, China

A novel self-template strategy is designed to synthesize uniform flowerlike N-doped hierarchical porous carbon networks (NHPCN) with high content of N (15.31 at.%), expanded interlayer spacing, ultrathin two-dimensional nano-sized subunits, and three-dimensional porous network structure, delivering outstanding sodium storage performances. 

2862–2868





Neglected interstitial space in malaria recurrence and treatment

Qiang Zhang1,2, Zhuo Ao1,2,*, Nan Hu1,3, Yuting Zhu1, Fulong Liao1,4, and Dong Han1,2,*

1 National Center for Nanoscience and Technology, China

2 University of Chinese Academy of Sciences, China

3 Chengde Medical University, China

4 China Academy of Chinese Medical Sciences, China

The interstitial space plays an important role that cannot be ignored in the recurrence and treatment of malaria, and may provide a potential way to prevent and treat infectious diseases.

2869–2878





Printable elastic silver nanowire-based conductor for washable electronic textiles

Hong-Wu Zhu, Huai-Ling Gao, Hao-Yu Zhao, Jin Ge, Bi-Cheng Hu, Jin Huang, and Shu-Hong Yu*

University of Science and Technology of China, China

Printable elastic conductor with conductivity of 3,668 S·cm–1 was developed for electronic textiles (e-textiles). One-step printing of ink could fabricate robust e-textiles, which could endure repeated stretching, folding, and machine washing. 

2879–2884


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《纳米研究》2020年第9期目录

《纳米研究》2020年第8期目录

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《纳米研究》2020年第6期目录

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《纳米研究》2020年第4期目录

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《纳米研究》2020年第2期目录

《纳米研究》2020年第1期目录



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