南京师范大学物理科学与技术学院报告视频--徐莉梅
报告人:徐莉梅
题目:Connectivity between structure and dynamic in glass-forming liquids
单位:北京大学
报告时间:2018年11月14日
报告地点:南京师范大学
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报告简介
The structural description for the link
between the fast vibrational dynamics and slow diffusive dynamics
inglass-forming systems is one of the most challenging issues in
physical science. Dynamic crossover is observed in many glass-forming
liquids. Different scenarios, such phase transition, partial
crystallization or glass transition, are proposed to explain such
phenomenon. In this talk, I will discuss the structural origin and its
correlation with dynamic transition in super cooledliquids.
Particularly, in a model of metallic supercooled liquid, we find that
local connectivity as an atomic-level structural order parameter tunes
the short-time vibrational excitations of the icosahedrally coordinated
particles and meanwhile modulates their long-time relaxation
dynamics changing from stretched to compressed exponentials, denoting a
dynamic transition from diffusive to hyperdiffusive motions. Our result
indicates that long-time dynamics has a structural origin, thus
suggesting a structural link the fast vibrational dynamics and the slow
structural relaxation in glassy materials.
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