图文目录｜GEE Volume 7, Issue 5 正式出版

Green Energy & Environment

Volume 7

Issue 5

Green Energy & Environment 2022年第七卷第五期已正式出版。本期共收录文章23篇，其中research highlight 1篇，review article 2篇，research paper 20篇。欢迎大家阅读、下载和投稿！

扫码获取整期内容

封面文章

中山大学严凯教授课题组研究论文——Green fabrication of nickel-iron layered double hydroxides nanosheets efficient for the enhanced capacitive performance该图以时空隧道为背景，主体为正在放电的超级电容器，超级电容器中蓝色薄片和黄色小球分别代表镍铁水滑石纳米片和电解液离子，密集的闪电展现出了镍铁水滑石纳米片优异的电容性能。封面左上部分展示了镍铁水滑石纳米片的晶体结构。该研究为高电容性能镍基水滑石纳米片的绿色构筑提供了实验基础和理论指导。

封底文章

厦门大学生物质燃料与化学品团队综述论文——Catalyst design strategy toward the efficient heterogeneously-catalyzed selective oxidation of 5-hydroxymethylfurfural

厦门大学生物质燃料与化学品团队对已建立的通过热催化氧化HMF的异相催化剂设计策略进行了综述，并分析了该领域当前面临的挑战和未来发展方向。该论文第一作者为刘淮博士，现工作于昆明理工大学，通讯作者为厦门大学唐兴副教授。

该作品以绿色森林和草地为背景，通过一股“风”将5-羟甲基糠醛氧化为高附加值的化学品，并最终得到“塑料瓶”。绿色森林和草地的背景表示原料来源于生物质，而带有不同催化剂的“风”象征着催化反应过程，而最终得到的“塑料瓶”表示可以通过这种方式生产可再生的化学品及材料。

图文目录

Research highlight

Exclusive CO₂-to-formate conversion over single-atom alloyed Cu-based catalysts

Junjun Li, Zhicheng Zhang*, Wenping Hu

https://doi.org/10.1016/j.gee.2021.11.004

Citation: J. Li, Z. Zhang, W. Hu, Green Energy Environ. 7 (2022) 855.

Review articles

Understanding of the electrochemical behaviors of aqueous zinc–manganese batteries: Reaction processes and failure mechanisms

Xinyu Luo, Wenchao Peng, Yang Li, Fengbao Zhang, Xiaobin Fan*In this review, a systematic discussion from three aspects of reaction processes, influencing factors, and failure mechanisms of aqueous zinc−manganese batteries have carried out, followed by issues haven't overcome and future research directions of mechanism research.

https://doi.org/10.1016/j.gee.2021.08.006

Citation: X. Luo, W. Peng, Y. Li, F. Zhang, X. Fan, Green Energy Environ. 7 (2022) 858-899.

Catalyst design strategy toward the efficient heterogeneously-catalyzed selective oxidation of 5-hydroxymethylfurfural

Huai Liu, Xing Tang*, Xianhai Zeng, Yong Sun, Xixian Ke, Tianyuan Li, Jiaren Zhang, Lu Lin

To improve the catalytic performance of the catalysts for the oxidation of 5-(hydroxymethyl)furfural (HMF), various catalyst design strategies have been developed to modify the geometric as well as the electronic configurations of the active centers, which have been systematically summarized in this review.

https://doi.org/10.1016/j.gee.2021.10.004

Citation: H. Liu, X. Tang, X. Zeng, Y. Sun, X. Ke, T. Li, J. Zhang, L. Lin, Green Energy Environ. 7 (2022) 900-932.

Research papers

Pd nanocluster-decorated CoFe composite supported on nitrogen carbon nanotubes as a high-performance trifunctional electrocatalyst

Revanasiddappa Manjunatha, Li Dong, Zibo Zhai, Jianyi Wang, Qianru Fu, Wei Yan*, Jiujun Zhang*

Pd nanocluster-decorated CoFe double-layered composite supported on nitrogen carbon nanotubes as a high-performance trifunctional electrocatalyst for water electrolysis and flexible Zinc-air battery applications.

https://doi.org/10.1016/j.gee.2020.12.005

Citation: R. Manjunatha, L. Dong, Z. Zhai, J. Wang, Q. Fu, W. Yan, J. Zhang, Green Energy Environ. 7 (2022) 933-947.

High retention volume covalent organic polymer for xenon capture: Dynamic separation of Xe and Kr

Qian Wang¹, Zhu Meng¹, Juntao Li, Shuming Peng*, Zhonghua Xiang*

A new covalent organic polymer COP-14 is developed for Xe/Kr separation. Suitable pore size and structure make it successfully separates low concentration Xe (350 ppm) and Kr (35 ppm) in dynamic breakthrough experiments.

https://doi.org/10.1016/j.gee.2020.12.010

Citation: Q. Wang, Z. Meng, J. Li, S. Peng, Z. Xiang, Green Energy Environ. 7 (2022) 948-956.

Na-MnO_x catalyzed aerobic oxidative cleavage of biomass-derived 1,2-diols to synthesis medium-chain furanic chemicals

Qing-Shan Kong, Xing-Long Li, Hong-Bo Shen, Hua-Jian Xu*, Yao Fu*

A strategy based on furanic platform chemicals was developed to synthesize a variety of high value-added furan-based compounds (diacids and esters, diols, hydroxy acids, acrylics), which simultaneously utilizes Na-MnO_x catalyst and practical catalytic methods.

https://doi.org/10.1016/j.gee.2020.12.007

Citation: Q.-S. Kong, X.-L. Li, H.-B. Shen, H.-J. Xu, Y. Fu, Green Energy Environ. 7 (2022) 957-964.

Magnetically enhancing diffusion for dendrite-free and long-term stable lithium metal anodes

Yongxiu Chen, Xiangyu Dou, Kai Wang, Yongsheng Han*

An introduction of external magnetic field vertical to the anode in lithium batteries leads to an enhanced even distribution of lithium ions at the surface, resulting in a dendrite-free lithium deposition.

https://doi.org/10.1016/j.gee.2020.12.014

Citation: Y. Chen, X. Dou, K. Wang, Y. Han, Green Energy Environ. 7 (2022) 965-974.

Scaled-up synthesis of defect-rich layered double hydroxide monolayers without organic species for efficient oxygen evolution reaction

Haoyuan Chi¹, Jingwen Dong¹, Tian Li¹, Sha Bai, Ling Tan, Jikang Wang, Tianyang Shen, Guihao Liu, Lihong Liu, Luyi Sun, Yufei Zhao*, Yu-Fei Song*

Through the separate nucleation and aging steps by using colloid mill reactor, monolayer LDHs were synthesized on a large scale. The defects-rich monolayer LDHs obtained by this method showed efficient electrocatalytic activity for oxygen evolution reaction.

https://doi.org/10.1016/j.gee.2020.12.013

Citation: H. Chi, J. Dong, T. Li, S. Bai, L. Tan, J. Wang, T. Shen, G. Liu, L. Liu, L. Sun, Y. Zhao, Y.-F. Song, Green Energy Environ. 7 (2022) 975-982.

Efficient catalytic removal of COS and H₂S over graphitized 2D micro-meso-macroporous carbons endowed with ample nitrogen sites synthesized via mechanochemical carbonization

Xun Kan¹, Guanqing Zhang¹, Yingying Luo, Fujian Liu*, Yong Zheng, Yihong Xiao, Yanning Cao, Chak-tong Au, Shijing Liang*, Lilong Jiang

Graphitized 2D micro-meso-macroporous carbons endowed with ultrahigh concentration of structural base nitrogen sites were synthesized by a one-step mechanochemical carbonization route. The samples act as high-efficient and stable catalysts for conversion of COS and H₂S to elemental sulfur.

https://doi.org/10.1016/j.gee.2020.12.016

Citation: X. Kan, G. Zhang, Y. Luo, F. Liu, Y. Zheng, Y. Xiao, Y. Cao, C.-t. Au, S. Liang, L. Jiang, Green Energy Environ. 7 (2022) 983-995.

Synthesis and fluorescent properties of quinoxaline derived ionic liquids

Jiaqi Wu, Lei Zhang, Jinxing Long, Qiang Zeng, Biaolin Yin*, Xuehui Li*

Based on a two-step process including a dual Schiff's base formation and a [RhCp∗Cl₂]₂-catalyzed oxidative C–H activation/annulation, a series of novel fluorescent isoquinolino [2,1-a]quinoxalin-5-ium ionic liquids (ILs) were prepared, showing dual or triple emissions due to the local excited state, charge transfer state and excited state proton transfer state of cation.

https://doi.org/10.1016/j.gee.2020.12.018

Citation: J. Wu, L. Zhang, J. Long, Q. Zeng, B. Yin, X. Li, Green Energy Environ. 7 (2022) 996-1005.

Building of multifunctional and hierarchical H_xMoO₃/PNIPAM hydrogel for high-efficiency solar vapor generation

Shuai Cao¹, Jingyun Jiang¹, Qingyong Tian*, Cang Guo, Xuzhe Wang, Kun Dai, Qun Xu*

A novel multifunctional and hierarchically nanostructured H_xMoO₃/PNIPAM hydrogel with photothermal activity and activate water capacity was achieved via one-step polymerization. The H_xMoO₃-contained hydrogel solar evaporator device fabricated here possesses a competitive water evaporation rate of 1.65 kg m^-2 h^-1 with the energy efficiency of 85.87% under 1 kW m^-2 irradiation.

https://doi.org/10.1016/j.gee.2020.12.012

Citation: S. Cao, J. Jiang, Q. Tian, C. Guo, X. Wang, K. Dai, Q. Xu, Green Energy Environ. 7 (2022) 1006-1013.

The influence of pore structures and Lewis acid sites on selective hydrogenolysis of guaiacol to benzene over Ru/TS-1

Yingying Xin, Zhaoxia Zheng, Zhicheng Luo*, Chengzhen Jiang, Shaofeng Gao, Zhihao Wang, Chen Zhao*

Pore structure properties of MFI coupled with abundant LAS (TS-1) as well as Ru NPs on the orifice of pores of TS-1 promotes the hydrogenolysis of lignin to aromatics, while BAS on Ru/MFI promotes the hydrogenation rates of aromatics.

https://doi.org/10.1016/j.gee.2020.12.024

Citation: Y. Xin, Z. Zheng, Z. Luo, C. Jiang, S. Gao, Z. Wang, C. Zhao, Green Energy Environ. 7 (2022) 1014-1023.

Engineering heterostructured Ni@Ni(OH)₂ core-shell nanomaterials for synergistically enhanced water electrolysis

Jun-Wei Zhang¹, Xian-Wei Lv¹, Tie-Zhen Ren*, Zheng Wang, Teresa J. Bandosz, Zhong-Yong Yuan*

By integrating into high-efficiency alkaline water electrolyzer equipment, the well-designed heterostructured core-shell Ni@Ni(OH)₂ bifunctional electrocatalysts with remarkable overall water splitting activity will open up a promising energy storage way for a highly renewable and sustainable power utilization system.

https://doi.org/10.1016/j.gee.2020.12.009

Citation: J.-W. Zhang, X.-W. Lv, T.-Z. Ren, Z. Wang, T.J. Bandosz, Z.-Y. Yuan, Green Energy Environ. 7 (2022) 1024-1032.

Synthesis of ordered hierarchically mesoporous/microporous carbon materials via compressed CO₂ for fructose-to-HMF transformation

Sen Luan, Wei Li*, Zanwu Guo, Wenxiu Li, Xiaojian Hou, Yi Song, Ran Wang, Qian Wang

A well-ordered hierarchically porous carbon (HPC) materiel was fabricated via dual soft-templating approach with compressed CO₂. The as-prepared HPC sample as the catalysis carrier exhibited the excellent catalytic performance with high HMF yield and accelerated reaction rate in the fructose-to-HMF transformation.

https://doi.org/10.1016/j.gee.2021.01.005

Citation: S. Luan, W. Li, Z. Guo, W. Li, X. Hou, Y. Song, R. Wang, Q. Wang, Green Energy Environ. 7 (2022) 1033-1044.

Ga₂OSe monolayer: A promising hydrogen evolution photocatalyst screened from two-dimensional gallium chalcogenides and the derived janus

Yu Cui, Mengyuan Li, Xiaoli Zhang, Sufan Wang, Yucheng Huang*

Density functional theory calculations were employed to screen the most effective photocatalyst for hydrogen evolution reaction among various two-dimensional gallium chalcogenides monolayers and the derived Janus monolayers.

https://doi.org/10.1016/j.gee.2021.01.002

Citation: Y. Cui, M. Li, X. Zhang, S. Wang, Y. Huang, Green Energy Environ. 7 (2022) 1045-1052.

Green fabrication of nickel-iron layered double hydroxides nanosheets efficient for the enhanced capacitive performance

Yuchen Wang, Zuo Chen, Man Zhang, Yaoyu Liu, Huixia Luo*, Kai Yan*

The nickel-iron layered double hydroxides (NiFe-LDHs) nanosheets were synthesized with a facile and eco-friendly ultrasonication-assisted methodology. The asymmetric supercapacitor assembled by NiFe-LDHs nanosheets and commercial activated carbon delivered a maximum specific energy of 49.13 Wh kg⁻¹.

https://doi.org/10.1016/j.gee.2021.01.019

Citation: Y. Wang, Z. Chen, M. Zhang, Y. Liu, H. Luo, K. Yan, Green Energy Environ. 7 (2022) 1053-1061.

Analyzing acetylene adsorption of metal–organic frameworks based on machine learning

Peisong Yang, Gang Lu*, Qingyuan Yang*, Lei Liu, Xin Lai, Duli Yu

The article uses machine learning methods to build an accurate prediction model of MOFs' adsorption capacity for C₂H₂. According to the classification model, effective design rules are extracted, which is of great significance to the selection and design of materials.

https://doi.org/10.1016/j.gee.2021.01.006

Citation: P. Yang, G. Lu, Q. Yang, L. Liu, X. Lai, D. Yu, Green Energy Environ. 7 (2022) 1062-1070.

Carbonized waste milk powders as cathodes for stable lithium–sulfur batteries with ultra-large capacity and high initial coulombic efficiency

Rabia Khatoon, Sanam Attique, Rumin Liu, Sajid Rauf, Nasir Ali, Luhong Zhang, Yu-Jia Zeng*, Yichuan Guo, Yusuf Valentino Kaneti*, Jongbeom Na, Haichao Tang, Hongwen Chen, Yang Tian, Jianguo Lu*

A trash to treasure approach to utilize waste milk powders as cathode in Li–S batteries. Cathode comprises of CMP/S (1:2) exhibited best electrochemical performance compared to CMP/S (1:1) and CMP/S (1:3).

https://doi.org/10.1016/j.gee.2021.01.007

Citation: R. Khatoon, S. Attique, R. Liu, S. Rauf, N. Ali, L. Zhang, Y.-J. Zeng, Y. Guo, Y.V. Kaneti, J. Na, H. Tang, H. Chen, Y. Tian, J. Lu, Green Energy Environ. 7 (2022) 1070-1083.

Vitamin B₉ derived nitrogen-doped graphene for metal-free aerobic oxidation of biomass-derived chemicals

Duan-Jian Tao*, Xin Zhao, Yanxin Wang, Xixi Liu, Hong-Ping Li, Zhang-Min Li, Yan Zhou, Ziliang Yuan, Zehui Zhang*

A superior carbocatalyst ultrahigh N-doped graphene (NG) was prepared by a novel self-sacrificial templating method of one-step annealing vitamin B₉. Systematic characterizations and quantum-chemical calculations further manifested that high contents of graphitic N and pyridinic N species in VB₉-NG-800 promoted the generation of •O₂⁻ active species from molecular oxygen effortlessly, resulting in excellent catalytic performance for aerobic oxidation.

https://doi.org/10.1016/j.gee.2021.01.008

Citation: D.-J. Tao, X. Zhao, Y. Wang, X. Liu, H.-P. Li, Z.-M. Li, Y. Zhou, Z. Yuan, Z. Zhang, Green Energy Environ. 7 (2022) 1084-1092.

A succinct enhanced luminescence strategy for fluorescent ionic liquids and the application for detecting CO₂

Siying Che, Jiachen Guo, Lu Gan, Qiaoxin Xiao, Haoran Li, Yuanbin She, Congmin Wang*

We reported a succinct enhanced luminescence strategy to reduce single-triplet energy split using the tunability of ionic liquids; thus up to 15 fold enhancements were achieved. This fluorescence ionic liquid has the advantages of a simple synthesis, convenient regulation and a remarkable effect, which has a good potential for detecting gas such as CO₂.

https://doi.org/10.1016/j.gee.2021.01.010

Citation: S. Che, J. Guo, L. Gan, Q. Xiao, H. Li, Y. She, C. Wang, Green Energy Environ. 7 (2022) 1093-1101.

Versatile control of concentration gradients in non-fullerene acceptor-based bulk heterojunction films using solvent rinse treatments

Chang-Mok Oh¹, Soyeong Jang¹, Jihoon Lee, Sung Heum Park*, In-Wook Hwang*

Material concentration gradient along the longitudinal direction of non-fullerene acceptor-based BHJ film, which is flexibly controlled by solvent rinse treatment using MeOH and n-hexane.

https://doi.org/10.1016/j.gee.2021.01.009

Citation: C.-M. Oh, S. Jang, J. Lee, S.H. Park, I.-W. Hwang, Green Energy Environ. 7 (2022) 1102-1110.

N-doped graphene anchored ultrasmall Ir nanoparticles as bifunctional electrocatalyst for overall water splitting

Wenqing Yao¹, Xian Jiang¹, Yulian Li, Cuiting Zhao, Linfei Ding, Dongmei Sun*, Yawen Tang*

The N-doped graphene anchored Ir nanoparticles (Ir/N-rGO) with ultrasmall particle size is synthesized via a simple hydrothermal method. Due to the synergy among ultrasmall Ir nanoparticle and N-doped rGO, the Ir/N-rGO exerts highly robust catalytic activity and durability toward the overall water splitting.

https://doi.org/10.1016/j.gee.2021.01.011

Citation: W. Yao, X. Jiang, Y. Li, C. Zhao, L. Ding, D. Sun, Y. Tang, Green Energy Environ. 7 (2022) 1111-1118.

Homodispersed B–CN/P–CN S-scheme homojunction for enhanced visible-light-driven hydrogen evolution

Dashui Yuan, Zongyuan Li, Xueru Chen, Jing Ding*, Hui Wan, Guofeng Guan*

In order to achieve highly dispersed composite photocatalysts with excellent charge separation efficiency, herein we investigate the pre-doping of Boron and Phosphorus into heptazine and two-step calcination. B–CN and P–CN formed a homodispersed S-scheme homojunction and thus produced a rich interface. Meanwhile, caused by Fermi energy levels equilibrium, the band bending constructed an S-scheme homojunction, which stimulated photogenerated electrons to transfer from CB of B–CN to VB of P–CN.

https://doi.org/10.1016/j.gee.2021.01.012

Citation: D. Yuan, Z. Li, X. Chen, J. Ding, H. Wan, G. Guan, Green Energy Environ. 7 (2022) 1119-1127.

相关推荐

01	GEE图文目录｜Volume 7, Issue 1 上线

02	GEE图文目录｜Volume 7, Issue 2 上线

03	GEE图文目录｜Volume 7, Issue 3 上线

04	GEE图文目录｜Volume 7, Issue 4 上线

05	GEE虚拟专刊｜Biofuel and bioenergy

06	GEE虚拟专刊｜Batteries

07	GEE虚拟专刊｜CO2 capture, storage, and utilization