【转载】图文目录|GEE Volume 7, Issue 3 上线
The following article is from 绿色能源与环境GEE Author GEE编辑部
Volume 7, Issue 3
Green Energy & Environment 2022年第七卷第三期已正式出版。本期共收录文章22篇,其中research highlight 1篇,short communication 1篇,review article 2篇,research paper 18篇。欢迎大家阅读、下载和投稿!
封面文章
江苏大学夏杰祥教授和朱文帅教授等人研究论文——MOFs derived FeNi3 nanoparticles decorated hollow N-doped carbon rod for high-performance oxygen evolution reaction。
封底文章
廊坊师范学院陈钰博士、卢艳红教授和中国人民大学牟天成教授等人综述——CO2 capture and conversion to value-added products promoted by MXene-based materials。
封面
封面故事:江苏大学夏杰祥教授、朱文帅教授课题组——Ni掺杂Fe基MOFs衍生FeNi3纳米粒子负载镂空结构氮杂碳材料用于电催化产氧。
该图以深海为背景,图中具有褶皱结构的黄色棒体展示了MOFs衍生碳材料的表面结构;红色球体代表具有优异催化活性的FeNi3纳米粒子。通过FeNi3纳米粒子负载镂空结构氮杂碳材料协同强化电荷传输、促进H2O分子活化,从而实现了高效电分解水产氧。该研究为合金纳米粒子负载碳基材料的精准制备提供了有效参考,促进了清洁能源的高效利用。
封底
封面故事:廊坊师范学院与中国人民大学合作综述——MXene助力二氧化碳捕集和转化,通讯作者为廊坊师范学院陈钰博士、卢艳红教授和中国人民大学牟天成教授。
天空美丽云朵中的二氧化碳被二维MXene材料吸附后经过热催化、光催化(太阳)、电催化(闪电)等路径转化为高附加值产物。两只破浪前行的帆船代表廊坊师范学院和中国人民大学,旨在弘扬中国传统合作共赢和勇于探索的精神。两列中国传统书法字“力争二零三零年前碳排放达峰,二零六零年前实现碳中和”是习近平总书记在第七十五届联合国大会上对世界的庄严承诺,彰显了中国“大国责任、大国担当、大国风范”的魄力与自信。两队祥鸟翱翔象征早日达到碳达峰和碳中和的目标和建设绿色低碳中国的雄心。图
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·Research highlight
Powerful qua-functional electrolyte additive for lithium metal batteries
Dawei Su*
https://doi.org/10.1016/j.gee.2021.10.005
·Short communication
Etching oxide overlayers of NiFe phosphide to facilitate surface reconstruction for oxygen evolution reaction
Tehua Wang, Xian-Zhu Fu*, Shuangyin Wang*
The oxide overlayers of NiFeP are etched by DBD-plasma, exposing the intrinsic surface. Etching the oxide overlayers can accelerate the surface reconstruction of NiFeP and facilitate the formation of key intermediate phases for OER.
https://doi.org/10.1016/j.gee.2021.03.005
湖南大学王双印教授&深圳大学符显珠教授:刻蚀处理加速电解水制氢·Review articles
The fabrication of atomically thin-MoS2 based photoanodes for photoelectrochemical energy conversion and environment remediation: A review
Zexu Chi, Jingyun Zhao, Yi Zhang, Han Yu*, Hongbing Yu*
This work summarized the recent process in the development of atomically thin-MoS2 (AT-MoS2) based PEC photoanodes in the application fields of water splitting and wastewater treatment. We illustrated the effective strategies for the preparation of high-performance AT-MoS2-based photoanode, and also provided guidance for the development of more effective AT-MoS2-based PEC photoanode.
https://doi.org/10.1016/j.gee.2021.05.002
南开大学于宏兵教授课题组:原子层薄MoS2基光阳极的制备及其在光电化学能源转换和环境修复方面的应用
CO2 capture and conversion to value-added products promoted by MXene-based materials
Yu Chen*, Chong Liu, Shien Guo, Tiancheng Mu*, Lei Wei, Yanhong Lu*
Capture, sensing and conversion of CO2 to value-added products by MXene-based materials are reviewed. Improvement of MXene synthesis and efficiency in a green method is also discussed for the purpose of achieving the green absorbent, sensor and catalyst.
https://doi.org/10.1016/j.gee.2020.11.008
·Research papers
Converting poly(ethylene terephthalate) waste into N-doped porous carbon as CO2 adsorbent and solar steam generator
Changyuan Song, Boyi Zhang, Liang Hao, Jiakang Min, Ning Liu, Ran Niu, Jiang Gong*, Tao Tang*
Without activations, poly(ethylene terephthalate) is facilely converted into N-doped porous carbon through stepwise crosslinking strategy by using melamine and molten salts ZnCl2/NaCl at 550 °C, which shows high-performance in CO2 capture and solar steam evaporation for producing drinkable water.
https://doi.org/10.1016/j.gee.2020.10.002
MOFs derived FeNi3 nanoparticles decorated hollow N-doped carbon rod for high-performance oxygen evolution reaction
Gaopeng Liu, Bin Wang, Lin Wang, Wenxian Wei, Yu Quan, Chongtai Wang, Wenshuai Zhu*, Huaming Li, Jiexiang Xia*
FeNi3 nanoparticles decorated hollow N-doped carbon rod derived from Ni-doped Fe-based MOFs via facile pyrolysis process. The as-prepared FeNiNC-550 elcetrocatalyst possesses an efficient oxygen evolution performance with a low overpotential and fast kinetic reaction rate.
https://doi.org/10.1016/j.gee.2020.10.007
Synergistic effect of NiII and Co/FeIII in doped mixed-valence phosphonate for enhancing electrocatalytic oxygen evolution
Juan-Juan Hou, Jian-Tao Yuan, Wei Zhang, Ying-Xia Wang, Xian-Ming Zhang*
A mixed-valence iron phosphonate (Fe3-ppat) has been constructed and applied to OER catalysis considered the potential active sites in pillars FeII(H2O)4(COO)2 and inorganic layers FeIII(μ2–OH)PO3. Optimized tri-metallic doping Fe1.7Co0.3Ni1.0-ppat possesses a minimum overpotential (291 mV), small Tafel slope (91.65 mV dec−1), and high stability up to 83 h. The enhanced catalytic performance could be mainly ascribed to the synergistic effect of NiII and Co/FeIII.
https://doi.org/10.1016/j.gee.2020.10.003
A facial synthesis of nitrogen-doped reduced graphene oxide quantum dot and its application in aqueous organics degradation
He Zhao1, Juehua Wang1, Zhuangjun Fan, Yongbing Xie*, Di Zhang, Shanshan Sun, Yi Zhang, Hongbin Cao*
One-step synthesis, doping and reduction of nitrogen-doped reduced graphene oxide quantum dots (N-rGQDs) was realized by adopting metal-free Fenton reaction using HA and H2O2 as the reactants. N-rGQDs with manipulative functional groups proved to be efficient candidates for pollution control.
https://doi.org/10.1016/j.gee.2020.10.008
Mechanistic aspects of facet-dependent CH4/C2+ selectivity over a χ-Fe5C2 Fischer–Tropsch catalyst
Thanh Hai Pham1, Junbo Cao1, Nan Song, Yueqiang Cao*, Bingxu Chen, Gang Qian, Xinggui Zhou, De Chen, Xuezhi Duan*
The geometry of χ-Fe5C2 surfaces shows negligible effects on CH4 formation but significantly affects C-C coupling. The adsorption energy of C+4H is demonstrated as a descriptor for CH4/C2+ selectivity of χ-Fe5C2 surfaces based on the established Brønsted–Evans–Polanyi relations.
https://doi.org/10.1016/j.gee.2020.10.015
Preparation of bimetal Co–Ni supported on Mg–Al oxide for chemocatalytic upgrading of tailored fermentation products to energy intensive fuels
Jiajun Liu, Kui Wu, Zhengke Li, Wensong Li, Yuqing Ning, Weiyan Wang*, Yunquan Yang*
Due to the formation of Co–Ni alloy, electron transfer from Co to Ni and large pore, bimetal Co–Ni supported catalyst presented high activity: acetone conversion and C5–C11 total selectivity in the aldol condensation of fermentation products (acetone–butanol–ethanol) reached to 76% and 90%, respectively.
https://doi.org/10.1016/j.gee.2020.10.011
NiCoP/NiOOH nanoflowers loaded on ultrahigh porosity Co foam for hydrogen evolution reaction under large current density
Yuantao Pei, Liang Huang*, Lei Han, Haijun Zhang*, Longhao Dong, Quanli Jia, Shaowei Zhang
On a highly porous Co foam prepared via freeze-drying, a self-supporting hierarchical NiCoP/NiOOH electrode was in-situ fabricated and exhibited superior HER performance in alkaline media under a current density over ~500 mA cm−2.
https://doi.org/10.1016/j.gee.2020.10.019
Cyclic oligourea synthesized from CO2: Purification, characterization and properties
Ruhui Shi, Haiyang Cheng*, Hongxiang Li, Peixuan Wu, Chao Zhang, Masahiko Arai, Fengyu Zhao*
A kind of cyclic oligourea was synthesized via polycondensation of CO2 and diamine followed by effective separation and purification.
https://doi.org/10.1016/j.gee.2020.10.016
In-situ growth of TiO2 film on carbonized eggshell membrane as 3D electrode for high-performance lithium storage
Xiao Yu, Xinyi Zhang, Yongjian Lai, Donghai Wang, Yong Liu*
A 3D electrode was successfully prepared by in-situ growing nanocrystalline TiO2 film on carbonized eggshell membrane, which favors continuous electron transport and electrolyte penetration along with Li+ ion diffusion in the whole electrode, leading to a superior lithium storage performance.
https://doi.org/10.1016/j.gee.2020.10.018
A mechanically durable, excellent recyclable 3D hierarchical Ni3S2@Ni foam photothermal membrane
Zhongping Yao, Kailun Yu, Mengyao Pan, Hongbo Xu*, Tianqi Zhao, Zhaohua Jiang
The photothermal membranes based on nanohierarchical Ni3S2/NF via grown in situ exhibited excellent solar absorption (93.13%) in the wavelength range of 250 nm to 2500 nm, reached 1.53 kg m-2 h-1 under one sun illumination and sustained anti-corrosion capacity for one month.
https://doi.org/10.1016/j.gee.2020.10.010
C2H2 semi-hydrogenation on the PdxMy cluster/graphdiyne catalysts: Effects of cluster composition and size on the activity and selectivity
Ying Wang1, Yamin Qi1, Maohong Fan*, Baojun Wang, Lixia Ling, Riguang Zhang*
C2H2 semi-hydrogenation to C2H4 on the PdxMy/GDY catalysts exhibits the composition and size dependence of the activity and selectivity. Pd1/GDY catalyst presents the best C2H4 selectivity and its formation activity compared to the previously reported catalysts so far in C2H2 semi-hydrogenation.
https://doi.org/10.1016/j.gee.2020.10.020
Ultra-small UiO-66-NH2 nanoparticles immobilized on g-C3N4 nanosheets for enhanced catalytic activity
Zhuizhui Su, Bingxing Zhang, Xiuyan Cheng, Fanyu Zhang, Qiang Wan, Lifei Liu, Xiuniang Tan, Dongxing Tan, Lirong Zheng, Jianling Zhang*
Herein, we synthesized UiO-66-NH2 nanoparticles in size of 8–15 nm that are immobilized on g-C3N4 nanosheets. Compared with the UiO-66-NH2 micronparticles (~0.2 μm), the ultra-small UiO-66-NH2 nanoparticles exhibit high catalytic activity for Meerwein–Ponndorf–Verley reaction owing to more unsaturated coordination positions and increased Lewis acidity.
https://doi.org/10.1016/j.gee.2020.10.023
Synthesis of dihydrocapsaicin and dihydrocapsiate exclusively from lignocellulosic platform chemicals
Yan-Bing Li1, Hui-Ying Guo1, Chen-Qiang Deng, Jin Deng*
The natural products dihydrocapsaicin and dihydrocapsaicin are exclusively synthesized from lignocellulose platform chemicals. All carbon atoms in the product are derived from lignocellulosic substrates, and the selective hydrodeoxygenation from carbonyl to methylene is achieved through a green process.
https://doi.org/10.1016/j.gee.2020.11.001
Two-dimensional metallic tantalum ditelluride with an intrinsic basal-plane activity for oxygen reduction: A microkinetic modeling study
Yu Wang, Kun Zhou*
Two-dimensional metallic TaTe2 nanosheet is proposed as a highly promising oxygen reduction reaction catalyst candidate with an intrinsic basal-plane activity based on density functional theory calculations, together with its underlying reaction mechanism/activity revealed by a comprehensive microkinetic modeling approach.
https://doi.org/10.1016/j.gee.2020.11.003
Mechanistic study of vacuum UV catalytic oxidation for toluene degradation over CeO2 nanorods
Muyan Wu, Yingguang Zhang, Haibao Huang*, Dennis Y.C. Leung*
Pure CeO2 was applied in the VUV catalytic oxidation system for toluene degradation involving VUV photolysis, UV-PCO, OZCO and UV-OZCO processes. The mechanism and synergetic effects of different processes were proposed.
https://doi.org/10.1016/j.gee.2020.11.002
Efficient photoelectrochemical conversion of CO2 to syngas by photocathode engineering
Sheng Chu1*, Pengfei Ou1, Roksana Tonny Rashid1, Yuyang Pan, Daolun Liang, Huiyan Zhang, Jun Song*
Efficient photoelectrochemical conversion of CO2 to syngas has been achieved by engineering of photocathode, which has a planar p-n Si junction for strong light harvesting, GaN nanowires for efficient electron extraction and transfer, and Au/TiO2 for rapid electrocatalytic syngas production.
https://doi.org/10.1016/j.gee.2020.11.015
麦吉尔大学Prof. Jun Song:光阴极设计助力CO2光电催化制合成气
Pomegranate-like porous NiCo2Se4 spheres with N-doped carbon as advanced anode materials for Li/Na-ion batteries
Xin Liu, Liwen Yang*, Guobao Xu, Juexian Cao*
3D pomegranate-like porous bimetallic spheres of nano-sized NiCo2Se4 particles as inner core and NiCo2Se4 layer/thin-walled N-doped carbon as inner/outer shell are demonstrated as high-perfomance anode materials for LIBs and NIBs.
https://doi.org/10.1016/j.gee.2020.08.012
Sunlight-controlled CO2 separation resulting from a biomass-based CO2 absorber
Shiming Zhang, Qianhao Pan, Yapei Wang*
A reversible CO2 capture system is fabricated by using sunlight as the energy source and modified sawdust as the CO2 absorbent. Using solar energy and wood chippings can minimize the additional CO2 output in both preparation and regeneration process of absorbent.
https://doi.org/10.1016/j.gee.2021.09.001
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