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Sci. China Chem. 2021年第8期目录

中国科学:化学 中国科学化学 2022-06-22
2021年第8期


Cover Story: 

Prof. Yuan-Zhu Zhang et al. developed a simple yet efficient post-modification approach via the Schiffbase condensation. Equipped with the chemical-active aldehyde (‒CHO) groups, the parent cyanide-bridged square [Fe2Co2] molecules were thus feasibly decorated with the alkyldiamines (NH2-(CH2)n-NH2), and encapsulated into discrete molecular capsules. Variable temperature single crystal X-ray diffraction, solid-state infrared/UV-Vis-NIR spectra and magnetic studies revealed the complete and abrupt thermo- and photo-induced ETCST property, and the bidirectional switching between the diamagnetic [FeIILS2CoIIILS2] state and the paramagnetic [FeIIILS2CoIIHS2] state (LS, low spin; HS, high spin) (see the article on pages 1340‒1348).


HIGHLIGHTS

Organic permeable base light-emitting transistor: a new concept device architecture for display technology

Haikuo Gao, Zhagen Miao, Huanli Dong

Sci. China Chem., 2021, 64(8), 12611262

 

Employ ionic liquid to stabilize black-phase formamidinium perovskites

SaisaiLi, Mingjian Yuan

Sci. China Chem., 2021, 64(8), 1263-1264(2021)

 

To make the dead lithium reusable

Xiaodong Lin, Quanfeng Dong

Sci. China Chem., 2021, 64(8), 12651266


REVIEWS 

Challenges and perspectives of covalent organic frameworks for advanced alkali-metal ion batteries

Jingyi Xu, Yifan Xu, Chenling Lai, Tingting Xia, Beining Zhang, Xiaosi Zhou

Sci. China Chem., 2021, 64(8), 12671282

 

Recent advances in the targeted fluorescent probes for the detection of metastatic bone cancer

Peng Wu, Daniel J. Siegwart, Hu Xiong

Sci. China Chem., 2021, 64(8), 12831296

 

COMMUNICATIONS

Photo-controllable room-temperature phosphorescence of organic photochromic polymers based on hexaarylbiimidazole

Yuanhao Li, Fan Gu, Bingbing Ding, Lei Zou, Xiang Ma

Sci. China Chem., 2021, 64(8), 12971301

 

Highly sensitive, sub-microsecond polymer photodetectors for blood oxygen saturation testing

Zijin Zhao, Baiqiao Liu, Changlin Xie, Yao Ma, Jian Wang, Ming Liu, Kaixuan Yang, Yunhua Xu, Jian Zhang, Weiwei Li, Liang Shen, Fujun Zhang

Sci. China Chem., 2021, 64(8), 13021309

 

Donor-conformation-dependent energy transfer for dual-color fluorescent probe with high-resolution imaging

Lifang Guo, Xin Jin, Hao Liu, Jiangnan Zhu, Zhiyun Zhang, Jianhua Su

Sci. China Chem., 2021, 64(8), 13101315


ARTICLES 

Eco-friendly co-catalyst-free cycloaddition of CO2 and aziridines activated by a porous MOF catalyst

Ying Shi, Jian Zhao, Hang Xu, Sheng-Li Hou, Bin Zhao

Sci. China Chem., 2021, 64(8), 13161322

 

Rapid and selective uranium extraction from aqueous solution under visible light inthe absence of solid photocatalyst

Shaojun Li, Yezi Hu, Zewen Shen, Yawen Cai, Zhuoyu Ji, Xiaoli Tan, Zhixin Liu, Guixia Zhao, Shuxian Hu, Xiangke Wang

Sci. China Chem., 2021, 64(8), 13231331

 

Conductive phthalocyanine-based metal-organic framework as a highly efficient electrocatalyst for carbon dioxide reduction reaction

Meng-Di Zhang, Duan-Hui Si, Jun-Dong Yi, Qi Yin, Yuan-Biao Huang, Rong Cao

Sci. China Chem., 2021, 64(8), 13321339

 

A smart post-synthetic route towards [Fe2Co2] molecular capsules with electron transfer and bidirectional switching behaviors

Lingyi Meng, Yi-Fei Deng, Shihao Liu, Zhiping Zheng, Yuan-Zhu Zhang

Sci. China Chem., 2021, 64(8), 13401348

 

Benzylicaroylation of toluenes with unactivated tertiary benzamides promoted by directed ortho-lithiation

Can-Can Bao, Yan-Long Luo, Hui-Zhen Du, Bing-Tao Guan

Sci. China Chem., 2021, 64(8), 13491354

 

Asymmetric catalytic 1,3-dipolar cycloaddition of α-diazoesters for synthesis of 1-pyrazoline-based spirochromanones and beyond

Peng Zhao, Zegong Li, Jun He, Xiaohua Liu, Xiaoming Feng

Sci. China Chem., 2021, 64(8), 13551360

 

Highly efficient NHC-iridium-catalyzed β-methylation of alcohols with methanol at low catalyst loadings

Zeye Lu, Qingshu Zheng, Guangkuo Zeng, Yunyan Kuang, James H. Clark, Tao Tu

Sci. China Chem., 2021, 64(8), 13611366

 

Palladium-catalyzed asymmetric carbamoyl-carbonylation of alkenes

Ziwen Feng, Qiuyu Li, Long Chen, Hequan Yao, Aijun Lin

Sci. China Chem., 2021, 64(8), 13671371

 

Chemoselective desulfurization-fluorination/bromination of carbonofluoridothioates for the O-trifluoromethylation and O-bromodifluoromethylation of alcohols

Jie Liu, Haonan Xiang, Lvqi Jiang, Wenbin Yi

Sci. China Chem., 2021, 64(8), 13721379

 

High-performance all-polymer solar cells enabled by a novel low bandgap non-fully conjugated polymer acceptor

Qunping Fan, Ruijie Ma, Tao Liu, Jianwei Yu, Yiqun Xiao, Wenyan Su, Guilong Cai, Yuxiang Li, Wenhong Peng, Tao Guo, Zhenghui Luo, Huiliang Sun, Lintao Hou, Weiguo Zhu, Xinhui Lu, Feng Gao, Ellen Moons, Donghong Yu, He Yan, Ergang Wang

Sci. China Chem., 2021, 64(8), 13801388

 

Hierarchically porous polymers with ultra-high affinity for bisphenol A enables high efficient water purification

Zelun Li, Juan Wang, Qian Chen, Kelong Ai, Lehui Lu

Sci. China Chem., 2021, 64(8), 13891400

 

Construction of CoS2 nanoparticles embedded in well-structured carbon nanocubes for high-performance potassium-ion half/full batteries

Yifan Xu, Jianlu Sun, Yanan He, Jianbo Li, Jianzhi Xu, Yingying Sun, Jiaying Liao, Xiaosi Zhou

Sci. China Chem., 2021, 64(8), 14011409

 

Well-balanced ambipolar diketopyrrolopyrrole-based copolymers for OFETs, inverters and frequency doublers

Jiaxin Yang, Qingqing Liu, Mengxiao Hu, Shang Ding, Jinyu Liu, Yongshuai Wang, DanLiu, Haikuo Gao, Wenping Hu, Huanli Dong

Sci. China Chem., 2021, 64(8), 14101416

 

In situ formation of ionically conductive nanointerphase on Si particles for stable battery anode

Xiaoxue Chen, Gaofeng Ge, Wenyu Wang, Bao Zhang, Jianjun Jiang, Xuelin Yang, Yuzhang Li, Li Wang, Xiangming He, Yongming Sun

Sci. China Chem., 2021, 64(8), 14171425

 

Sub-nanometer supramolecular rectifier based on the symmetric building block with destructive σ-interference

Longfeng Huang, Yu Zhou, Yaorong Chen, Jingyao Ye, Junyang Liu, Zongyuan Xiao, Chun Tang, Haiping Xia, Wenjing Hong

Sci. China Chem., 2021, 64(8), 14261433

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