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Sci. China Chem. 2020年第11期目录

中国科学化学 中国科学化学 2022-04-29
Science China Chemistry2020年第11期

[Cover Story] Inspired by alchemy, product yield is closely related to the chemical reactions between batch feeds, somewhat analogous to the interaction between water molecules and a catalyst’s active sites. If the active sites possess suitable orbitals for water molecule coupling and activation, the corresponding reaction kinetics can be boosted. In light of that, Prof. Gongming Wang et al. introduced oxygen dopants with stronger electronegativity into Ni3N to create more unoccupied orbitals on Ni sites with lower energy and superior orientation for efficient water adsorption and dissociation. The regulation of interfacial electronic coupling may provide new opportunities for the rational design of hydrogen evolution reaction catalysts among others (see the article on pages 1563–1569)..






SPECIAL TOPIC: Electrocatalysis & Energy Science


EDITORIAL

Preface: Special topic on electrocatalysis & energy science

Changzheng Wu, Gang Wu & Guihua Yu

Sci. China Chem., 2020, 63(11): 1515–1516


REVIEWS

Advanced transition metal/nitrogen/carbon-based electrocatalysts for fuel cell applications

Tang Tang, Liang Ding, Zhe Jiang, Jin-Song Hu & Li-Jun Wan

Sci. China Chem., 2020, 63(11): 1517–1542


Local structure engineering for active sites in fuel cell electrocatalysts

Han Cheng, Renjie Gui, Si Liu, Yi Xie & Changzheng Wu

Sci. China Chem., 2020, 63(11): 1543–1556

 

COMMUNICATIONS

Intrinsically high efficiency sodium metal anode

Yifang Zhang, Qiuwei Shi, Yiren Zhong & Hailiang Wang

Sci. China Chem., 2020, 63(11): 1557–1562

 

ARTICLES

Orbital-regulated interfacial electronic coupling endows Ni3N with superior catalytic surface for hydrogen evolution reaction

Yanyan Fang, Da Sun, Shuwen Niu, Jinyan Cai, Yipeng Zang, Yishang Wu, Linqin Zhu, Yufang Xie, Yun Liu, Zixuan Zhu, Amirabbas Mosallanezhad, Di Niu, Zheng Lu, Junjie Shi, Xiaojing Liu, Dewei Rao, Gongming Wang & Yitai Qian

Sci. China Chem., 2020, 63(11): 1563–1569

 

Mo2C@3D ultrathin macroporous carbon realizing efficient and stable nitrogen fixation

Zhiwei Fang, Desiree Fernandez, Nana Wang, Zhongchao Bai & Guihua Yu

Sci. China Chem., 2020, 63(11): 1570–1577





HIGHLIGHTS

An innovative armour-strategy for robust superhydrophobic surfaces

Xuetao Xu, Lianxin Shi & Shutao Wang

Sci. China Chem., 2020, 63(11): 1578–1579

 

Electrochemical urea production directly from N2 and CO2 in ambient aqueous media

Run Shi & Tierui Zhang

Sci. China Chem., 2020, 63(11): 1580–1581

 

Overall water splitting over conjugated polymer photocatalysts with crystal facets modulated

Yu Qi & Fuxiang Zhang

Sci. China Chem., 2020, 63(11): 1582–1583

 

Vicinal Na+ as structure guardians of atomically dispersed Ru catalysts in hydrogenation reactions

Chunyang Dong & Ding Ma

Sci. China Chem., 2020, 63(11): 1584–1585

 

MINI REVIEWS

Recent advances in nickel-catalyzed reductive hydroalkylation and hydroarylation of electronically unbiased alkenes

Xiao-Xu Wang, Xi Lu, Yan Li, Jia-Wang Wang & Yao Fu

Sci. China Chem., 2020, 63(11): 1586–1600

 

FEATURE ARTICLES

Quasi-MOF-immobilized metal nanoparticles for synergistic catalysis

Liyu Chen, Nobuko Tsumori & Qiang Xu

Sci. China Chem., 2020, 63(11): 1601–1607

 

COMMUNICATIONS

A uranyl based coordination polymer showing response to low-dosage ionizing radiations down to 10Gy

Jian Xie, Yaxing Wang, Wei Liu, Chengyu Liang, Yugang Zhang, Lanhua Chen, Daopeng Sheng, Zhifang Chai & Shuao Wang

Sci. China Chem., 2020, 63(11): 1608–1612

 

Synthesis of non-classical heteroaryl C-glycosides via Minisci-type alkylation of N-heteroarenes with 4-glycosyl-dihydropyridines

Qingbing Wang, Juan Duan, Pingping Tang, Gong Chen & Gang He

Sci. China Chem., 2020, 63(11): 1613–1618

 

Combinatorial synthesis of redox-responsive cationic polypeptoids for intracellular protein delivery application

Zhicheng Le, Tong Xiao, Zhijia Liu, Xingliang Liu, Hong Liu, Lixin Liu & Yongming Chen

Sci. China Chem., 2020, 63(11): 1619–1625

 

ARTICLES

Three-dimensional conjugated macrocycle with large polyaromatic blocks constructed by post-π-extension

Shun-He Liu, Hao Hou, Ze-Ying Deng, Xin-Rong Wang, Chun Tang, Yang-Yang Ju, Liu-Bin Feng & Yuan-Zhi Tan

Sci. China Chem., 2020, 63(11): 1626–1631


Soluble triarylamine functionalized symmetric viologen for all-solid-state electrochromic supercapacitors

Yanling Zhuang, Weiwei Zhao, Longlu Wang, Feiyang Li, Weikang Wang, Shujuan Liu, Wei Huang & Qiang Zhao

Sci. China Chem., 2020, 63(11): 1632–1644

 

Resonance hosts for high efficiency solution-processed blue and white electrophosphorescent devices

Huanhuan Li, Jibiao Jin, Yuan Xiang, Ying Zhang, Ye Tao, Mingguang Li, Qin Xue, Guohua Xie, Wei Huang & Runfeng Chen

Sci. China Chem., 2020, 63(11): 1645–1651

 

Visible-light-induced regioselective cross-dehydrogenative coupling of 2-isothiocyanatonaphthalenes with amines using molecular oxygen

Ziyu Gan, Guoqing Li, Xiaobo Yang, Qiuli Yan, Guiyun Xu, Gaoyang Li, Yuan-Ye Jiang & Daoshan Yang

Sci. China Chem., 2020, 63(11): 1652–1658

 

Spiro-conjugated indenodiarylethenes: enabling steric-induced electronic tuning of photochromic and photoluminescent properties by spiro-conjugation

Tingting Huang, Hongyu Liu, Yawen Bang, Yanpei Wang, Yuan Liang, Xinhao Wang, Yang Zhang, Sheng Xie, Zebing Zeng & Ben Zhong Tang

Sci. China Chem., 2020, 63(11): 1659–1665

 

Tuning the intermolecular interaction of A2-A1-D-A1-A2 type non-fullerene acceptors by substituent engineering for organic solar cells with ultrahigh VOC of ~1.2 V

Xiaochen Wang, Ailing Tang, Jing Yang, Mengzhen Du, Jianfeng Li, Gongqiang Li, Qiang Guo & Erjun Zhou

Sci. China Chem., 2020, 63(11): 1666–1674

 

Concerted regulation on vertical orientation and film quality of two-dimensional ruddlesden-popper perovskite layer for efficient solar cells

Xianglan Tang, Xueying Wang, Ting Hu, Qingxia Fu, Xiaotian Hu, Zengqi Huang, Shuqin Xiao & Yiwang Chen

Sci. China Chem., 2020, 63(11): 1675–1683

 

Interlayer ligand engineering of β-Ni(OH)2 for oxygen evolution reaction

Junying He, Yuqin Zou, Yucheng Huang, Chenhui Li, Yanbo Liu, Ling Zhou, Chung-Li Dong, Xia Lu & Shuangyin Wang

Sci. China Chem., 2020, 63(11): 1684–1693


Enabling AIEgens close assembly in tumor-overexpressed protein cluster for boosted image-guided cancer surgery

Junxiao Gao, Jun Li, Daohe Wei, Han Yang, Yue Duan, Yue Zhang, Xiaoqun Gong, Hanjie Wang, Dan Ding, Xiaoli Wu & Jin Chang

Sci. China Chem., 2020, 63(11): 1694–1702

 

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