《中国科学：材料科学》2023年第1期

Cover Story 

Featuring high theoretical capacity and wide operating voltage window, bismuth oxide (Bi₂O₃) has drawn great attention as a promising battery-type anode. Its slow reaction kinetics and poor cyclability, however, impedes its performance in energy storage devices. Recently, Chen and coworkers fabricated Bi-Bi₂O₃ nanoparticles encapsulated in carbon nanorods (Bi-Bi₂O₃@C_NR) by employing bismuth-based metal-organic frameworks (CAU-17) as both the template and precursor through pyrolysis and deliberate oxidation-state modulation. The Bi-Bi₂O₃@C_NR anode exhibited an enhanced electrical conductivity, a fast reaction kinetics, a high specific capacity, and an extended lifespan in the sodium sulfate electrolyte. The robust, in situ derived carbon matrix working as a rod-like nanoreactor, as well as the introduction of metallic bismuth into the bismuth oxide crystalline structure, enables the Bi-Bi₂O₃@C_NR electrode to deliver a package of optimal electrochemical performance (see the article on page 106).

REVIEW

柔性钙钛矿发光二极管: 进展, 挑战与展望

Jin-Tao Wang, Shu-Zhuang Wang, Yu-Hang Zhou, Yan-Hui Lou (娄艳辉), Zhao-Kui Wang (王照奎)

Sci China Mater, 2023, 66(1): 1–21

REVIEW

仿生学中介电聚合物复合材料的研究进展

Hui Chi, Wen He, Danying Zhao, Rujun Ma (马儒军), Yunhe Zhang (张云鹤), Zhenhua Jiang

Sci China Mater, 2023, 66(1): 22–34

REVIEW

悬浮于石墨烯空位/孔洞中的独立纳米结构

Yu Liu, Huy Q. Ta, Xiaoqin Yang, Yue Zhang, Junhua Zhou, Qitao Shi, Mengqi Zeng, Thomas Gemming, Barbara Trzebicka, Lei Fu, Mark H. Rümmeli

Sci China Mater, 2023, 66(1): 35–50

ARTICLE

氮掺杂Ti3C2Tx MXene纳米片包覆的SiOx实现储锂性能提升

Kaiyuan Zhang, Dan Zhao, Zhao Qian (钱钊), Xin Gu (顾鑫), Jian Yang (杨剑), Yitai Qian

Sci China Mater, 2023, 66(1): 51–60

ARTICLE

A novel PbSe@CNTs anode material based on dual conversion-alloying mechanism for sodium-ion batteries

基于转化-合金化机制的钠离子电池PbSe@CNTs负极材料

Dongdong Zhao, Ning Zhang (张宁), Xiaoying Zhao, Ningbo Liu, Bin Qin, Mande Qiu, Liubin Wang (王刘彬)

Sci China Mater, 2023, 66(1): 61–68

ARTICLE

电子堆积工程调控二硒化镍纳米片助力具有快速动力学的钠离子电池

Jing Liu, Juan Xie, Huilong Dong, Huaixin Wei, Chencheng Sun (孙陈诚), Jun Yang (杨骏), Hongbo Geng (耿洪波)

Sci China Mater, 2023, 66(1): 69–78

ARTICLE

钠离子电池Na0.62K0.05Mn0.7Ni0.2Co0.1O2正极材料: 钾离子掺杂且{001}面稳定的中空多面体

Zhi-Xiong Huang, Xue-Li Zhang, Xin-Xin Zhao, Yong-Li Heng, Ting Wang, Hongbo Geng (耿洪波), Xing-Long Wu (吴兴隆)

Sci China Mater, 2023, 66(1): 79–87

ARTICLE

钠离子高电压正极Na0.7Ni0.35Sn0.65O2材料在空气中的劣化及修复机理

Ruiwang Zhang, Jianing Liang, Cheng Zeng, Jiajun Chen, Ying Ma, Tianyou Zhai, Huiqiao Li (李会巧)

Sci China Mater, 2023, 66(1): 88–96

ARTICLE

具有优越镍-锌电池性能的低结晶镍钴氢氧化物

Chun Yang, Zhiwei Peng, Qingyu Zhao, Rui Liu, Shilin Yun, Zhiqiang Zhang, Meiqiang Fan, Haijie Cao, Hai-Chao Chen (陈海潮)

Sci China Mater, 2023, 66(1): 97–105

ARTICLE

Bismuth-based metal-organic frameworks derived rod-like nanoreactors for neutral aqueous battery-type anode

铋基有机金属框架衍生的棒状纳米反应器用于中性水系电池型负极

Mingze Xu, Shuaiqi Gong, Yanli Niu, Kaiyan Zhang, Tao Liu (刘韬), Zuofeng Chen (陈作锋)

Sci China Mater, 2023, 66(1): 106–117

ARTICLE

用于微电池的超高功率密度铁氧硫化物薄膜

Bingyuan Ke, Xinghui Wang (王星辉), Shoulin Cheng, Wangyang Li, Renming Deng, Congcong Zhang, Jie Lin, Qingshui Xie, Dong-Liang Peng (彭栋梁)

Sci China Mater, 2023, 66(1): 118–126

ARTICLE

设计并构建I型SnSe2/ZnS异质结构提升其光电化学探测及水分解性能

Xinyi Xue, Chunhui Lu, Mingwei Luo, Taotao Han, Yuqi Liu, Yanqing Ge, Wen Dong, Xinlong Xu (徐新龙)

Sci China Mater, 2023, 66(1): 127–138

ARTICLE

1D/2D CeO2/ZnIn2S4 Z-scheme heterojunction photocatalysts for efficient H2 evolution under visible light

1D/2D CeO2/ZnIn2S4 Z-scheme异质结光催化剂实现高效可见光分解水制氢

Renqian Jiang, Liang Mao, Yulong Zhao, Junying Zhang, Eugene B. Chubenko, Vitaly Bondarenko, Yanwei Sui, Xiuquan Gu (顾修全), Xiaoyan Cai (蔡晓燕)

Sci China Mater, 2023, 66(1): 139–149

ARTICLE

用于高效C2醇氧化电催化的三金属钯-银-铜纳米片组装体

Ze Li, Xianzhuo Lao, Likang Yang, Aiping Fu, Peizhi Guo (郭培志)

Sci China Mater, 2023, 66(1): 150–159

ARTICLE

引入共价型氮化钒来提高氮掺杂碳的亲电性以促进氧还原反应

Shidong Li, Zechao Zhuang, Lixue Xia, Jiexin Zhu, Ziang Liu, Ruhan He, Wen Luo, Wenzhong Huang, Changwei Shi, Yan Zhao (赵焱), Liang Zhou (周亮)

Sci China Mater, 2023, 66(1): 160–168

ARTICLE

Solvent-free synthesis of Co@NC catalyst with Co-N species as active sites for chemoselective hydrogenation of nitro compounds

无溶剂合成以Co-N物种为活性位点的Co@NC催化剂用于芳香硝基化合物选择加氢

Haisheng Wei, Huaxing Song, Yujing Ren, Xiaorui Yan, Geqian Fang, Wenhua Wang, Wanzhong Ren, Mingyuan Zhu, Jian Lin (林坚)

Sci China Mater, 2023, 66(1): 169–178

ARTICLE

双功能Cu-TiO2/CuO光催化剂用于大规模协同处理含有机污染物和重金属离子的废水

Yang Ding, Soumyajit Maitra, Chunhua Wang, Runtian Zheng, Tarek Barakat, Subhasis Roy, Li-Hua Chen (陈丽华), Bao-Lian Su (苏宝连)

Sci China Mater, 2023, 66(1): 179–192

ARTICLE

Si-CMOS-compatible 2D PtSe2-based self-driven photodetector with ultrahigh responsivity and specific detectivity

与硅基CMOS兼容且具有超高响应率和比探测率的二维二硒化铂自驱动光电探测器

Peng Ye, Han Xiao, Qinghai Zhu, Yuhan Kong, Youmei Tang, Mingsheng Xu (徐明生)

Sci China Mater, 2023, 66(1): 193–201

ARTICLE

利用AlGaN耦合作用调控WS2层内和层间谷激子

Xinlong Zeng, Wenyu Kang, Xiaowen Zhou, Linglong Li, Yuanzheng Xia, Haiyang Liu, Chengbiao Yang, Yaping Wu (吴雅苹), Zhiming Wu (吴志明), Xu Li (李煦), Junyong Kang

Sci China Mater, 2023, 66(1): 202–210

ARTICLE

Efficient ion-slicing of 4-inch GaAs thin film for Si-based hetero-integration with ultra-smooth surface

用于制备具有超光滑表面异质集成4英寸硅基砷化镓薄膜的高效离子剥离技术

Jialiang Sun, Jiajie Lin (林家杰), Tingting Jin, Chaodan Chi, Min Zhou, Robert Kudrawiec, Jin Li, Tiangui You, Xin Ou (欧欣)

Sci China Mater, 2023, 66(1): 211–218

ARTICLE

Growth of the orthorhombic phase and inhibition of charge injection in ferroelectric HfO2-based MFIS memory devices with a high-permittivity dielectric seed layer

HfO2铁电薄膜基MFIS存储结构中的高κ介电晶籽层效应研究: 铁电正交相生长和界面电荷注入抑制

Yan Zhang, Dao Wang, Jiali Wang, Chunlai Luo, Ming Li, Yushan Li, Ruiqiang Tao, Deyang Chen, Zhen Fan, Ji-Yan Dai, Guofu Zhou, Xubing Lu (陆旭兵), Jun-Ming Liu

Sci China Mater, 2023, 66(1): 219–232

ARTICLE

类沸石结构分子：极具潜力的二维介电材料

Lixin Liu, Pengyu Li, Yinghe Zhao (赵英鹤), Haiyang Song, Teng Liu, Huiqiao Li, Tianyou Zhai (翟天佑)

Sci China Mater, 2023, 66(1): 233–240

ARTICLE

Controllable volatile-to-nonvolatile memristive switching in single-crystal lead-free double perovskite with ultralow switching electric field

具有超低开关电场的可控的易失性至非易失性单晶无铅双钙钛矿忆阻器

Qi You, Fu Huang, Feier Fang, Jiaqi Zhu, Yue Zheng, Shaofan Fang, Bo Zhou, Henan Li, Cheng Han (韩成), Yumeng Shi (时玉萌)

Sci China Mater, 2023, 66(1): 241–248

ARTICLE

Excellent cryogenic magnetocaloric properties in heavy rare-earth based HRENiGa2 (HRE = Dy, Ho, or Er) compounds

重稀土HRENiGa2 (HRE = Dy, Ho或Er)化合物的优异低温磁热性能

Dan Guo, Luis M. Moreno-Ramírez, Jia-Yan Law, Yikun Zhang (张义坤), Victorino Franco

Sci China Mater, 2023, 66(1): 249–256

ARTICLE

Centrosymmetric to noncentrosymmetric structural transformation in a superconducting high-entropy alloy due to carbon addition

碳添加引起一种超导高熵合金的中心对称到非中心对称结构转变

Guorui Xiao, Qinqing Zhu, Wuzhang Yang, Yanwei Cui, Shijie Song, Guang-Han Cao, Zhi Ren (任之)

Sci China Mater, 2023, 66(1): 257–263

ARTICLE

Transparent conductive SnO2 thin films via resonant Ta doping

Vedaste Uwihoreye, Zhenni Yang, Jia-Ye Zhang, Yu-Mei Lin, Xuan Liang, Lu Yang, Kelvin H. L. Zhang

Sci China Mater, 2023, 66(1): 264–271

ARTICLE

Interface interaction-mediated design of tough and conductive MXene-composited polymer hydrogel with high stretchability and low hysteresis for high-performance multiple sensing

基于界面相互作用的具有高伸展和低滞后性的坚韧导电MXene基复合聚合物水凝胶用于高性能多功能传感器

Xinliang Wang, Na Li, Juanjuan Yin, Xiaoming Wang, Linli Xu, Tifeng Jiao (焦体峰), Zhihui Qin (秦志辉)

Sci China Mater, 2023, 66(1): 272–283

ARTICLE

基于氧化钒的动态超表面

Yue Li, Jianliang Xie, Longjiang Deng, Bo Peng (彭波)

Sci China Mater, 2023, 66(1): 284–290

ARTICLE

Suppressing triplet exciton quenching by regulating the triplet energy of crosslinkable hole transport materials for efficient solution-processed TADF OLEDs

用通过调节交联空穴传输材料三线态能级实现溶液法制备高效的热活化延迟荧光有机电致发光二极

Yifei Yan, Fei Zhang, Hongli Liu, Xianggao Li, Shirong Wang (王世荣)

Sci China Mater, 2023, 66(1): 291–299

‍

ARTICLE

Wavefront-controllable all-silicon terahertz meta-polarizer

波前可控的全硅太赫兹超构起偏器

Jitao Li, Zhen Yue, Jie Li, Chenglong Zheng, Jingyu Liu, Fan Yang, Hui Li, Yating Zhang (张雅婷), Yan Zhang (张岩), Jianquan Yao (姚建铨)

Sci China Mater, 2023, 66(1): 300–308

ARTICLE

Effect of structural modifications on the spectral and lasing characteristics of truxene-cored starbursts with/without diphenylamine end-cappers

二苯胺端基修饰对三并茚基多臂结构共轭大分子激光增益材料体系激光特性的影响

Cheng-Fang Liu, Qun Yu, Tingting Lu, Qian Luo, Shuoguo Chen, Ziming Guo, Xu Liu, Wen-Yong Lai (赖文勇)

Sci China Mater, 2023, 66(1): 309–318

ARTICLE

超微孔碳吸附剂实现天然气中丙烷和乙烷的高选择性提取

Fuqiang Chen, Kaiqing Guo, Xinlei Huang, Zhiguo Zhang, Qiwei Yang, Yiwen Yang, Qilong Ren, Zongbi Bao (鲍宗必)

Sci China Mater, 2023, 66(1): 319–326

ARTICLE

A clean dry transfer of hexagonal boron nitride with improved oxidation resistance

一种提升六方氮化硼抗氧化性的洁净干转移方法

Xuemei Li, Zhengyang Li, Luqiao Qi, Yuyang Long, Baowen Li, Jidong Li, Jianxin Zhou, Yan Shi, Jun Yin (殷俊), Wanlin Guo

Sci China Mater, 2023, 66(1): 327–334

ARTICLE

Ultralarge-scale anomalous phase separation discovered in a Cr–Fe–Co–Ni–Zr high-entropy metallic glass system

Cr-Fe-Co-Ni-Zr高熵金属玻璃体系中的超大尺度反常相分离

Yao Huang, Su-Ting Weng, Hong-Yu Jiang, Ze-Peng Liu, Xiao-Zhi Liu, Yu-Tian Wang, Lai-Quan Shen, Bo-Yang Sun, Fu Yang, Zi-Jian Wang, Yong-Hao Sun, Bao-An Sun, Zhen Lu, Xue-Feng Wang, Hai-Yang Bai (白海洋)

Sci China Mater, 2023, 66(1): 335–342

ARTICLE

一种预测无机晶体形成能的高精度泛化模型

Yingzong Liang, Mingwei Chen, Yanan Wang, Huaxian Jia, Tenglong Lu, Fankai Xie, Guanghui Cai, Zongguo Wang, Sheng Meng (孟胜), Miao Liu (刘淼)

Sci China Mater, 2023, 66(1): 343–351

ARTICLE

Reprogramming tumor-immune cell communication with a radiosensitive nanoregulator for immunotherapy

放射敏感的纳米调节剂重新编程肿瘤-免疫细胞通讯用于免疫治疗

Yuanyuan Chen, Shujie Liu, Peng Gao, Wei Pan, Mingwan Shi, Jianbo Wang (王建波), Na Li (李娜), Bo Tang (唐波)

Sci China Mater, 2023, 66(1): 352–362

ARTICLE

A hybrid of lactic acid bacteria and metal-organic frameworks potentiates photodynamic immunotherapy for hypoxia-targeted tumor eradication

一种乳酸菌-金属有机框架复合物用于强化肿瘤乏氧光动力和免疫治疗

Tianzhong Li, Jinyong Wang, Tongkai Chen, Swelm Wageh, Ahmed A. Al-Ghamdi, Jiangtian Yu, Zhongjian Xie (谢中建), Han Zhang (张晗)

Sci China Mater, 2023, 66(1): 363–374

ARTICLE

Stenhouse adduct molecular switch for enzymatic reactions remotely controlled with near-infrared light

近红外光遥控酶催化反应的分子开关纳米平台

Ke Li, Miao-Deng Liu, Qian-Xiao Huang, Chuan-Jun Liu (刘传军), Xian-Zheng Zhang (张先正)

Sci China Mater, 2023, 66(1): 375–384

ARTICLE

Acceptor-donor-acceptor structured phototheranostics for near-infrared II fluorescent and photoacoustic imaging-guided photodynamic and photothermal synergistic therapy

受体-供体-受体结构光疗试剂用于近红外二区荧光成像和光声成像引导的光动力和光热联合治疗

Baoling Li, Yabing Gan, Ke Yang, E Pang, Xiaojie Ren, Shaojing Zhao, Dan He, Fuwen Zhao (赵富稳), Benhua Wang, Peng Yin (尹鹏), Xiangzhi Song, Minhuan Lan (蓝敏焕)

Sci China Mater, 2023, 66(1): 385–394

ARTICLE

An ultrasound activable metal-phenolic network nano-antibiotics for in vivo on-site infection therapy

超声激活的金属多酚配位纳米抗生素在体内抗耐药菌治疗中的应用

Chang Lu, Ye Tian, Hao Tian, Bei Li, Bo Peng, Jun Zheng (郑军), Yunlu Dai (代云路)

Sci China Mater, 2023, 66(1): 395–406

LETTER

银掺杂镍的硫醇盐类团簇用于非均相电催化二氧化碳还原

Fan Tian, Wangxuan Li, Wenjin Guo, Guangfang Li, Rong Chen (陈嵘)

Sci China Mater, 2023, 66(1): 407–412

LETTER

低温条件下反常的铁电保持

Aiji Wang, Yu Tian, Minchuan Liang, Yiwen Hu, Mingyue Liu, Shujia Liao, Yinshu Wang, Kui Jin, Jing Wang (王静), Jinxing Zhang (张金星)

Sci China Mater, 2023, 66(1): 413–418

HIGHLIGHT

Supercompressible conductive hydrogels in harsh environments

Markus Antonietti

Sci China Mater, 2023, 66(1): 419–420

2022年全12期文章目录（点击链接可查看各期目录）

《中国科学：材料科学》2022年第12期 专辑: 面向碳中和的能源转换《中国科学：材料科学》2022年第11期
《中国科学：材料科学》2022年第10期
《中国科学：材料科学》2022年第9期《中国科学：材料科学》2022年第8期 专辑: 柔性智能材料《中国科学：材料科学》2022年第7期《中国科学：材料科学》2022年第6期《中国科学：材料科学》2022年第5期《中国科学：材料科学》2022年第4期《中国科学：材料科学》2022年第3期《中国科学：材料科学》2022年第2期《中国科学：材料科学》2022年第1期

点击阅读全文，了解更多