Sci. China Chem. 2019年第11期——“有机自由基化学”专刊目录

Science China Chemistry

2019年第11期

SPECIAL ISSUE: Organic Free Radical Chemistry

The cover picture is contributed by Prof. Chen Zhu et al. from Soochow University. Pls see the article on pages 1507-1511 for details.

【延伸阅读】苏州大学朱晨教授课题组：烯基自由基参与的远程惰性C(sp3)-H键三氟甲硫基烯基化反应

EDITORIAL

Special issue on organic free radical chemistry
Mukund P. Sibi, Chaozhong Li & Ning Jiao
Sci China Chem, 2019, 62(11): 1423–1424

REVIEWS
The role of organic electron donors in the initiation of BHAS
base-induced coupling reactions between haloarenes and arenes
Andrew J. Smith, Darren L. Poole & John A. Murphy
Sci China Chem, 2019, 62(11): 1425–1438

Photocatalytic single electron transfer reactions on TiO₂ semiconductor
Hideto Miyabe & Shigeru Kohtani
Sci China Chem, 2019, 62(11): 1439–1449

The xanthate route to all-carbon quaternary centers
Béatrice Quiclet-Sire & Samir Z. Zard
Sci China Chem, 2019, 62(11): 1450–1462

Recent advances in radical-mediated [2+2+m] annulation of 1,n-enynes
Chong-Hui Xu, Yang Li, Jin-Heng Li, Jian-Nan Xiang & Wei Deng
Sci China Chem, 2019, 62(11): 1463–1475

Radical cascade reactions of unsaturated C–C bonds involving migration
Ge Zhang, Yang Liu, Jinbo Zhao, Yan Li & Qian Zhang
Sci China Chem, 2019, 62(11): 1476–1491

COMMUNICATIONS

Nickel-catalyzed reductive coupling of glucosyl halides with aryl/vinyl halides enabling β-selective preparation of C-aryl/vinyl glucosides
Jiandong Liu, Chuanhu Lei & Hegui Gong
Sci China Chem, 2019, 62(11): 1492–1496

Photocatalytic decarboxylative coupling between α-oxocarboxylic acids and alkenes
Ziyue Chen, Fangling Lu, Feng Yuan, Juanjuan Sun, Linyu Du, Zhen Li, Meng Gao, Renyi Shi & Aiwen Lei
Sci China Chem, 2019, 62(11): 1497–1500

Synthesis of 1,3-benzothiazines by intramolecular dehydrogenative C–S cross-coupling in a flow electrolysis cell
Chong Huang & Hai-Chao Xu
Sci China Chem, 2019, 62(11): 1501–1503

【延伸阅读】厦门大学徐海超教授：连续流动电化学脱氢C–S偶联合成苯并噻嗪

ARTICLES
Radical-mediated hydroalkylation of 2-vinylpyrrolidine derivatives: a versatile entry into indolizidine alkaloids
Sankar Rao Suravarapu, Bettina Peter & Philippe Renaud
Sci China Chem, 2019, 62(11): 1504–1506

Regioselective introduction of vinyl trifluoromethylthioether to remote unactivated C(sp3)–H bonds via radical translocation cascade
Shuo Wu, Xinxin Wu, Zhen Wu & Chen Zhu
Sci China Chem, 2019, 62(11): 1507–1511

【延伸阅读】苏州大学朱晨教授课题组：烯基自由基参与的远程惰性C(sp3)-H键三氟甲硫基烯基化反应

Enantioconvergent photoredox radical-radical coupling catalyzed by a chiral-at-rhodium complex
Zijun Zhou, Xin Nie, Klaus Harms, Radostan Riedel, Lilu Zhang & Eric Meggers
Sci China Chem, 2019, 62(11): 1512–1518

Visible-light-mediated external-reductant-free reductive cross coupling of benzylammonium salts with (hetero)aryl nitriles

Meng Miao, Li-Li Liao, Guang-Mei Cao, Wen-Jun Zhou & Da-Gang Yu
Sci China Chem, 2019, 62(11): 1519–1524

【延伸阅读】四川大学余达刚教授课题组：可见光介导无外加还原剂的苄基季铵盐和（杂）芳腈的还原偶联反应

Br-radical-mediated [3+2] annulation: synthesis of 2-bromomethyl substituted alkenylcyclopentanes by the reaction of alkenyl cyclopropanes with allyl bromides under photo irradiation
Takahide Fukuyama, Takashi Kippo, Kanako Hamaoka & Ilhyong Ryu
Sci China Chem, 2019, 62(11): 1525–1528

Cu/chiral phosphoric acid-catalyzed radical-initiated asymmetric aminosilylation of alkene with hydrosilane
Yang Zeng, Xiao-Dong Liu, Xian-Qi Guo, Qiang-Shuai Gu, Zhong-Liang Li, Xiao-Yong Chang & Xin-Yuan Liu
Sci China Chem, 2019, 62(11): 1529–1536

【延伸阅读】南方科技大学刘心元课题组：铜和手性磷酸催化烯烃的不对称自由基胺硅烷基化反应

Iodine(III) reagent (ABX–N₃)-induced intermolecular anti-Markovnikov hydroazidation of unactivated alkenes

Xiaonan Li, Pinhong Chen & Guosheng Liu
Sci China Chem, 2019, 62(11): 1537–1541

Trifluoromethyl radical triggered radical cyclization of N-benzoyl ynamides leading to isoindolinones
Maud Cassé, Christian Nisole, Héloïse Dossmann, Yves Gimbert, Jean-Marie Fourquez, Laure Haberkorn, Cyril Ollivier & Louis Fensterbank
Sci China Chem, 2019, 62(11): 1542–1546

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Guest Editors

Prof. Mukund P. Sibi earned his Ph.D. degree from the City University of New York. After postdoctoral studies, he began his independent career at North Dakota State University where he is currently a University Distinguished Professor. His research focus is on radical chemistry, development of enantioselective reactions, total synthesis, and green chemistry.

Prof. Chaozhong Li (李超忠教授) received his B.Sc degree from University of Science and Technology of China in 1988 and Ph.D. degree from Shanghai Institute of Organic Chemistry (SIOC), Chinese Academy of Sciences (CAS) in 1993. After about 5 years’ postdoctoral experience at Iowa State University, he returned to SIOC in 1999 and was promoted to Full Professor in 2000. His research interests focus on radicals in organic Synthesis.

Prof. Ning Jiao(焦宁教授) received his Ph.D. degree (2004) with Prof. Shengming Ma at Shanghai Institute of Organic Chemistry (SIOC). He then spent 2004-2006 as an Alexander von Humboldt Postdoctoral Fellow with Prof. Manfred T. Reetz at Max Planck Institute für Kohlenforschung. In 2007, he joined the faculty at Peking University as an Associate Professor, and was promoted to Full Professor in 2010. His current research efforts are focused on: 1) Aerobic oxidation, Oxygenation, Nitrogenation, and Halogenation reactions; 2) The first-row transition metal catalysis and the inert chemical bonds activation.

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