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SCC Virtual Issue on Organic Synthesis

中国科学化学 中国科学化学 2022-04-29

Asymmetric Synthesis

Reviews

Recent advance in asymmetric synthesis with CO2 

Chuan-Kun Ran, Xiao-Wang Chen, Yong-Yuan Gui, Jie Liu, Lei Song, Ke Ren & Da-Gang Yu

Sci. China Chem., 2020, 63(10): 1336–1351


Articles

Enantioselective three-component Ugi reaction catalyzed by chiral phosphoric acid 

Jian Zhang, Yi-Yan Wang, He Sun, Shao-Yu Li, Shao-Hua Xiang & Bin Tan

Sci. China Chem., 2020, 63(1): 47–54


Reversal of diastereoselectivity in palladium-arene interaction directed hydrogenative desymmetrization of 1,3-diketones

Chang-Bin Yu, Heng-Ding Wang, Bo Song, Hong-Qiang Shen, Hong-Jun Fan & Yong-Gui Zhou

Sci. China Chem., 2020, 63(2): 215–221


Highly stereoselective construction of polycyclic benzofused tropane scaffolds and their latent bioactivities: bifunctional phosphonium salt-enabled cyclodearomatization process

Jian-Ping Tan, Xiaojie Li, Yuan Chen, Xianle Rong, Lixiang Zhu, Chunhui Jiang, Kai Xiao & Tianli Wang

Sci. China Chem., 2020, 63(8): 1091–1099


Synergy of activating substrate and introducing C-H···O interaction to achieve Rh2(II)-catalyzed asymmetric cycloisomerization of 1,n-enynes 

Rui Wu, Kai Chen, Jun Ma, Zhi-Xiang Yu, Shifa Zhu

Sci. China Chem., 2020, 63(9): 1230–1239


Communications

Development of unique dianionic Ir(III) CCC pincer complexes with a favourable spirocyclic NHC framework

Zhi-Bo Yan, Kun-Long Dai, Bin-Miao Yang, Zi-Hao Li, Yong-Qiang Tu, Fu-Min Zhang, Xiao-Ming Zhang, Meng Peng, Qi-Long Chen & Ze-Ran Jing

Sci. China Chem., 2020, 63(12): 1761–1766


 

C–H/C–C/C–N/C–Si Activation

Reviews

Recent advances in nickel-catalyzed reductive hydroalkylation and hydroarylation of electronically unbiased alkenes

Xiao-Xu Wang, Xi Lu, Yan Li, Jia-Wang Wang & Yao Fu

Sci. China Chem., 2020, 63(11):1586–1600

Articles

Amides as surrogates of aldehydes for C–C bond formation: amide-based direct knoevenagel-type condensation reaction andrelated reactions

Wei Ou & Pei-Qiang Huang

Sci. China Chem., 2020, 63(1):11–15


Transformations of N-arylpropiolamides to indoline-2,3-diones and acids via C≡C triple bond oxidative cleavage and C(sp2)–H functionalization

Ming-Bo Zhou, Yang Li, Xuan-Hui Ouyang & Jin-Heng Li

Sci. China Chem., 2020, 63(2):222–227


Ni-catalyzed direct alcoholysis of N-acylpyrrole-type tertiary amides under mild conditions

Hang Chen, Dong-Huang Chen & Pei-Qiang Huang

Sci. China Chem., 2020, 63(3):370–376


Neighbouring carbonyl group-assisted sequential 1,2-azide and 1,4-oxygen migrations of vinyl azides leading to α-azido ketones

Yi Gai, Yongquan Ning, Paramasivam Sivaguru, Xiaomeng Li, Yue Zhao, Jiayi Wu & Xihe Bi

Sci. China Chem., 2020, 63(4):460–466


Catalyst-controlled diastereoselective ring-opening formal [3+2]-cycloadditions of arylvinyl oxirane 2,2-diesters with cyclic N-sulfonyl imines

Jun-An Xiao, Xiu-Liang Cheng, Hai Peng, Jin-Lian Li, Zhen-Zhen Xie, Wen-Qiang Chen, Zhi-Ping Liu, Qi Xiao, Wei Su & Hua Yang

Sci. China Chem., 2020, 63(6):785–791


Silicon-mediated enantioselective synthesis of structurally diverse-amino acid derivatives

Jun-Han Ma, Li Li, Yu-Li Sun, Zheng Xu, Xing-Feng Bai, Ke-Fang Yang, Jian Cao, Yu-Ming Cui, Guan-Wu Yin & Li-Wen Xu

Sci. China Chem., 2020, 63(8):1082–1090


Communications

Para-selective borylation of monosubstituted benzenes using a transient mediator

Jie Wu, Zengwei Wang, Xiao-Yue Chen, Yichen Wu, Daoming Wang, Qian Peng & Peng Wang

Sci. China Chem., 2020, 63(3):336–340


Palladium-catalyzed ortho-C–H silylation of biaryl aldehydes using a transient directing group

Yong-Jie Wu, Qi-Jun Yao, Hao-Ming Chen, Gang Liao & Bing-Feng Shi

Sci. China Chem., 2020, 63(7):875–880


Palladium-catalyzed asymmetric allylic C–H alkylation of 1,4-dienes and glycine Schiff bases

Tian-Ci Wang, Pu-Sheng Wang & Liu-Zhu Gong

Sci. China Chem., 2020, 63(4):454–459


Organic Free-radical Chemistry

Communications

Predictable site-selective radical fluorination of tertiary ethers 

Junyang Ma, Wentao Xu & Jin Xie

Sci. China Chem., 2020, 63(2): 187–191


Synthesis of non-classical heteroaryl C-glycosides via minisci-type alkylation of Nheteroarenes with 4-glycosyl-dihydropyridines

Qingbing Wang, Juan Duan, Pingping Tang, Gong Chen & Gang He

Sci. China Chem., 2020, 63(11): 1613–1618


 

Visible Light-driven Organic Synthesis

Reviews

A review of enantioselective dual transition metal/photoredox catalysis

Hong-Hao Zhang, Hui Chen, Chengjian Zhu & Shouyun Yu

Sci. China Chem., 2020, 63(5): 637–647


Articles

Visible-light-promoted oxidative coupling of vinylarenes with cyclic ethers

Golam Kibriya, Debashis Ghosh & Alakananda Hajra

Sci. China Chem., 2020, 63(1): 42–46


Visible-light-induced regioselective cross-dehydrogenative coupling of 2-isothiocyanatonaphthalenes with amines using molecular oxygen isothiocyanatonaphthalenes with amines using molecular oxygen 

Ziyu Gan, Guoqing Li, Xiaobo Yang, Qiuli Yan, Guiyun Xu, Gaoyang Li, Yuan-Ye Jiang & Daoshan Yang

Sci. China Chem., 2020, 63(11): 1652–1658


Communications

Photoredox/palladium-cocatalyzed enantioselective alkylation of secondary benzyl carbonates with 4-alkyl-1,4-dihydropyridines 

Xu Shen, Linlin Qian & Shouyun Yu

Sci. China Chem., 2020, 63(5): 687–691


General Organic Synthesis

Articles

A C2-symmetric triple [5]helicene based on N-annulated triperylene hexaimide for chiroptical electronics 

Zetong Ma, Thorsten Winands, Ningning Liang, Dong Meng, Wei Jiang, Nikos L. Doltsinis & Zhaohui Wang

Sci. China Chem., 2020, 63(2): 208–214


Elaboration of phosphoramidite ligands enabling palladium-catalyzed diastereo- and enantioselective all carbon [4+3] cycloaddition 

Xing Zheng, Hao Sun, Wu-Lin Yang & Wei-Ping Deng

Sci. China Chem., 2020, 63(7): 911–916


Naphthalene diimide based near-infrared luminogens with aggregation-induced emission characteristics for biological imaging and high mobility ambipolar transistors

De Guo, Lin Li, Xianqi Zhu, Martin Heeney, Jing Li, Lichun Dong, Qingsong Yu, Zhihua Gan, Xinggui Gu & Luxi Tan

Sci. China Chem., 2020, 63(9): 1198–1207


Communications

Palladium-catalyzed regioselective cascade reaction of carbon dioxide, amines and allenes for the synthesis of functionalized carbamates 

Wenfang Xiong, Ruixiang Cheng, Bowen Wu, Wanqing Wu, Chaorong Qi & Huanfeng Jiang

Sci. China Chem., 2020, 63(3): 331–335


A practical access to fluoroalkyl thio(seleno)-functionalized bicyclo[1.1.1]pentanes 

Zhen Wu, Yaohui Xu, Jige Liu, Xinxin Wu & Chen Zhu

Sci. China Chem., 2020, 63(8): 1025–1029


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